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  • Synthesis and characterization of novel unsymmetrical and symmetrical 3-halo- or 3-methoxy-substituted 2-dibenzoylamino-1,4-naphthoquinone derivatives.

Synthesis and characterization of novel unsymmetrical and symmetrical 3-halo- or 3-methoxy-substituted 2-dibenzoylamino-1,4-naphthoquinone derivatives.

Molecules (Basel, Switzerland) (2013-02-06)
Yakini Brandy, Nailah Brandy, Emmanuel Akinboye, Malik Lewis, Claudia Mouamba, Seshat Mack, Ray J Butcher, Alan J Anderson, Oladapo Bakare
ABSTRACT

Symmetrical and unsymmetrical 3-halo- or 3-methoxy- substituted 2-dibenzoylamino- 1,4-naphthoquinone analogs were synthesized with an average yield of 45% via sodium hydride promoted bis-acylation of 2-amino-3-chloro-1,4-naphthoquinone, 2-amino-3-bromo-1,4-naphthoquinone and 2-amino-3-methoxy-1,4-naphthoquinone.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
1,4-Naphthoquinone, 97%
Sigma-Aldrich
1,4-Naphthoquinone, purum, ≥96.5% (HPLC)