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Merck
CN

Development of a method for recycling of CRT funnel glass.

Environmental technology (2013-02-27)
Tung-Chai Ling, Chi-Sun Poon
ABSTRACT

Finding better solutions to manage and recycle cathode-ray tube (CRT) glass is crucial for reducing the environmental threats due to the disposal of the glass. In this paper, the results of a laboratory study on developing a method for removing lead from crushed funnel glass surface and re-utilizing the treated glass in cement mortar are presented. The results demonstrate that nitric acid at 3-5% concentration levels can be used to remove most of the lead from the crushed funnel glass surface and render it as non-hazardous waste based on toxicity characteristics leaching procedure (TCLP) testing. It is noted that the particle size of glass and number of treatment cycles are significant factors affecting lead extraction. The study further demonstrated that it is feasible to utilize up to 100% of treated funnel glass as a replacement for natural sand for producing cement mortar.

MATERIALS
Product Number
Brand
Product Description

Supelco
Nitric acid concentrate, 0.1 M HNO3 in water (0.1N), eluent concentrate for IC
Sigma-Aldrich
Nitric acid, 70%, purified by redistillation, ≥99.999% trace metals basis
Sigma-Aldrich
Nitric acid, puriss. p.a., ≥65% (T)
Sigma-Aldrich
Nitric acid, ACS reagent, ≥90.0%
Sigma-Aldrich
Nitric acid, puriss., 64-66%
Sigma-Aldrich
Nitric acid, ACS reagent, 70%
Sigma-Aldrich
Nitric acid, puriss. p.a., 65.0-67.0%
Sigma-Aldrich
Nitric acid, puriss. p.a., reag. ISO, reag. Ph. Eur., ≥65%