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  • Sulfur and iron co-doped titanoniobate nanosheets: a novel efficient solid acid catalyst for alcoholysis of styrene epoxide at room temperature.

Sulfur and iron co-doped titanoniobate nanosheets: a novel efficient solid acid catalyst for alcoholysis of styrene epoxide at room temperature.

Chemical communications (Cambridge, England) (2013-07-17)
Lihong Zhang, Chenhui Hu, Junfeng Zhang, Liyuan Cheng, Zheng Zhai, Jing Chen, Weiping Ding, Wenhua Hou
ABSTRACT

Sulfur and iron co-doped titanoniobate nanosheets were prepared and evaluated in alcoholysis of styrene epoxide. The resultant co-doped catalyst exhibited excellent catalytic performance (yield of 99% with methanol as the nucleophile in only 1 h at room temperature) and may act as a promising candidate in many acid-catalyzed reactions.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Niobium(V) oxide, −325 mesh, 99.9% trace metals basis
Sigma-Aldrich
Niobium(V) oxide, 99.99% trace metals basis
Supelco
Styrene, analytical standard
Sigma-Aldrich
Styrene, ReagentPlus®, contains 4-tert-butylcatechol as stabilizer, ≥99%