sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

GF88937162

Nickel, foil, light tested, 100x100mm, thickness 0.007mm, 99.95%

GF64818850

Nickel, foil, not light tested, 25x25mm, thickness 0.0005mm, temporary acrylic support, 99.95%

GF45284081

Nickel, foil, not light tested, 100x100mm, thickness 0.004mm, hard, 99%

GF25257573

Nickel, wire reel, 50m, diameter 0.25mm, annealed, 99%

GF60907091

Nickel, wire reel, 20m, diameter 1.0mm, hard, 99.98%

GF23066197

Nickel, tube, 200mm, outside diameter 0.8mm, inside diameter 0.64mm, wall thickness 0.08mm, as drawn, 99.5%

GF62726597

Nickel, foil, 6mm disks, thickness 0.005mm, as rolled, 99.9%

GF39981437

Nickel, wire reel, 5m, diameter 0.25mm, as drawn, 99.99+%

GF34661774

Nickel, foil, 25mm disks, thickness 0.0125mm, annealed, 99%

GF01966732

Nickel, wire reel, 5m, diameter 1.0mm, as drawn, 99%

GF54123476

Nickel, wire reel, 500m, diameter 0.125mm, hard, 99.98%

GF57335148

Nickel, wire reel, 50m, diameter 0.5mm, hard, 99.98%

GF07573989

Nickel, wire reel, 5m, diameter 2.0mm, hard, 99.98%

GF88108623

Nickel, wire reel, 500m, diameter 0.15mm, as drawn, 99%

GF07174762

Nickel, foil, 6mm disks, thickness 0.05mm, annealed, 99%

GF50019937

Nickel, foil, 6mm disks, thickness 0.009mm, 99.95%

GF39346038

Nickel, foil, 6mm disks, thickness 0.015mm, 99.9%

GF71613828

Nickel, foil, 6mm disks, thickness 0.025mm, 99.9%

GF82923374

Nickel, foil, 4mm disks, thickness 0.3mm, as rolled, 100%

GF92598283

Nickel, foil, 5m coil, thickness 0.0125mm, 99.9%

GF90933431

Nickel, foil, 50mm disks, thickness 0.075mm, as rolled, 99.98%

GF28868439

Nickel, foil, 50mm disks, thickness 0.005mm, as rolled, 99.9%

GF40497970

Nickel, foil, 5m coil, thickness 0.15mm, coil width 12mm, annealed, 99%

GF39029306

Nickel, foil, 50mm disks, thickness 0.025mm, annealed, 99%

GF34210820

Nickel, foil, 50mm disks, thickness 0.025mm, 99.9%