sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

GF37795214

Nickel, foil, 4mm disks, thickness 0.075mm, annealed, 99%

GF34612567

Nickel, foil, 5m coil, thickness 0.05mm, coil width 2mm, annealed, 99%

GF72595659

Nickel, foil, 5m coil, thickness 0.05mm, annealed, 99%

GF88726168

Nickel, foil, light tested, 25x25mm, thickness 0.009mm, 99.95%

GF15891600

Nickel, foil, light tested, 100x100mm, thickness 0.0125mm, annealed, 99%

GF50270318

Nickel, foil, 8mm disks, thickness 0.075mm, annealed, 99%

GF04088651

Nickel, foil, light tested, 100x100mm, thickness 0.05mm, as rolled, 99.98%

GF56836682

Nickel, foil, 150x150mm, thickness 0.15mm, annealed, 99%

GF29119800

Nickel, foil, light tested, 100x100mm, thickness 0.05mm, 99.9%

GF72121159

Nickel, foil, light tested, 150x150mm, thickness 0.025mm, 99.9%

GF99921505

Nickel, foil, 25mm disks, thickness 0.5mm, annealed, 99.98%

GF14758241

Nickel, foil, light tested, 200x200mm, thickness 0.075mm, as rolled, 99.98%

GF70289859

Nickel, foil, light tested, 100x100mm, thickness 0.05mm, as rolled, 99.99+%

GF39346038

Nickel, foil, 6mm disks, thickness 0.015mm, 99.9%

GF52817014

Nickel, foil, 8mm disks, thickness 0.0075mm, 99.9%

GF56472723

Nickel, foil, 6mm disks, thickness 0.1mm, annealed, 99%

GF97410955

Nickel, foil, 100x100mm, thickness 1.0mm, as rolled, 99.99+%

GF51728463

Nickel, foil, 8mm disks, thickness 0.025mm, 99.9%

GF50084311

Nickel, foil, 25mm disks, thickness 0.30mm, as rolled, 99.98%

GF03831195

Nickel, foil, light tested, 25x25mm, thickness 0.038mm, 99.9%

GF19518712

Nickel, foil, light tested, 150x150mm, thickness 0.05mm, annealed, 99%

GF71182245

Nickel, foil, 150x150mm, thickness 0.1mm, annealed, 99%

GF00842789

Nickel, foil, 100x100mm, thickness 0.30mm, as rolled, 99.98%

GF03980864

Nickel, foil, 8mm disks, thickness 0.50mm, annealed, 99%

GF09816521

Nickel, foil, 8mm disks, thickness 0.038mm, 99.9%

GF03244687

Nickel, foil, light tested, 25x25mm, thickness 0.05mm, as rolled, 100%