sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules.

Natural product reports (2014-02-28)

Egor Geist, Andreas Kirschning, Thomas Schmidt

ABSTRACT

This Highlight covers the current status of relatively unexplored sp(3)-sp(3) cross-coupling reactions with particular focus on natural product and related syntheses.

MATERIALS

Product Number

Brand

Product Description

267074

Sigma-Aldrich

Nickel, rod, diam. 6.35 mm, ≥99.99% trace metals basis

357626

Sigma-Aldrich

Nickel, wire, diam. 0.5 mm, ≥99.9% trace metals basis

357588

Sigma-Aldrich

Nickel, foil, thickness 0.1 mm, 99.98% trace metals basis

357553

Sigma-Aldrich

Nickel, foil, thickness 0.5 mm, 99.98% trace metals basis

577995

Sigma-Aldrich

Nickel, nanopowder, <100 nm avg. part. size, ≥99% trace metals basis

GF83400364

Nickel, foil, not light tested, 100x100mm, thickness 0.002mm, 99.95%

GF89307063

Nickel, foil, not light tested, 25x25mm, thickness 0.001mm, 99.95%

GF88937162

Nickel, foil, light tested, 100x100mm, thickness 0.007mm, 99.95%

GF64818850

Nickel, foil, not light tested, 25x25mm, thickness 0.0005mm, temporary acrylic support, 99.95%

GF64926153

Nickel, foil, 10mm disks, thickness 0.05mm, 99.9%

GF96533758

Nickel, rod, 100mm, diameter 10.0mm, 99.99+%

GF09790869

Nickel, foil, 0.5m coil, thickness 1.0mm, annealed, 99%

GF55570192

Nickel, wire reel, 100m, diameter 0.125mm, annealed, 99.98%

GF46767167

Nickel, foil, 0.3m coil, thickness 0.125mm, as rolled, 99.99+%

GF49268526

Nickel, tube, 5mm, outside diameter 0.8mm, inside diameter 0.5mm, wall thickness 0.15mm, hard, 99.5%

GF16075638

Nickel, foil, 0.5m coil, thickness 0.15mm, coil width 12mm, annealed, 99%

GF05706389

Nickel, foil, 10mm disks, thickness 0.05mm, annealed, 99%

GF98554078

Nickel, tube, 500mm, outside diameter 3.25mm, inside diameter 3.05mm, wall thickness 0.1mm, hard, 99.5%

GF28849371

Nickel, foil, 0.5m coil, thickness 0.05mm, 99.9%

GF37939506

Nickel, mesh, 30x30mm, nominal aperture 0.34mm, thickness 0.025mm, wire diameter 0.041mm, 70 wires/inch, open area 80%, electro-formed mesh, 99.9%

GF16508246

Nickel, foil, 10mm disks, thickness 0.0125mm, annealed, 99%

GF16803075

Nickel, foil, 2m coil, thickness 0.125mm, annealed, 99.98%

GF73152233

Nickel, foil, 0.5m coil, thickness 0.15mm, annealed, 99%

GF25123159

Nickel, foil, 0.5m coil, thickness 0.0125mm, annealed, 99%

GF13212807

Nickel, pellets, 50g, max. size 5mm, 99.99+%

GF74649695

Nickel, foil, 2m coil, thickness 0.3mm, annealed, 99%

GF90435887

Nickel, foil, 0.5m coil, thickness 0.20mm, annealed, 99%

GF67355624

Nickel, foil, 0.5m coil, thickness 0.025mm, 99.9%

GF95772910

Nickel, foil, 4mm disks, thickness 0.025mm, 99.9%

GF92543564

Nickel, foil, 150x300mm, thickness 0.25mm, annealed, 99.98%