Palladium-catalysed hydroxylation and alkoxylation.

Palladium-catalysed hydroxylation and alkoxylation.

Chemical Society reviews (2011-06-07)

Stephan Enthaler, Anna Company

ABSTRACT

The formation of oxygen-carbon bonds is one of the fundamental transformations in organic synthesis. In this regard the application of palladium-based catalysts has been extensively studied during recent years. Nowadays it is an established methodology and the success has been proven in manifold synthetic procedures. This tutorial review summarizes the advances on palladium-catalysed C-O bond formation, means hydroxylation and alkoxylation reactions.

MATERIALS

Product Number

Brand

Product Description

GF57528816

Palladium, foil, not light tested, 25x25mm, thickness 0.006mm, 99.95%

GF55245821

Palladium, foil, not light tested, 100x100mm, thickness 0.025mm, as rolled, 99.99+%

GF69074916

Palladium, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.75%

GF55924241

Palladium, foil, not light tested, 25x25mm, thickness 0.025mm, as rolled, 99.99+%

686468

Sigma-Aldrich

Palladium, nanopowder, <25 nm particle size (TEM), ≥99.5%

267120

Sigma-Aldrich

Palladium, foil, thickness 0.025 mm, 99.9% trace metals basis

373206

Sigma-Aldrich

Palladium, evaporation slug, diam. × L 0.6 cm × 0.6 cm, 99.95% trace metals basis

203998

Sigma-Aldrich

Palladium, powder or granules, 99.99% trace metals basis

203939

Sigma-Aldrich

Palladium, powder, 99.995% trace metals basis

464651

Sigma-Aldrich

Palladium, powder, <75 μm, 99.9% trace metals basis

326666

Sigma-Aldrich

Palladium, powder, <1 μm, ≥99.9% trace metals basis

267082

Sigma-Aldrich

Palladium, sponge, 99.9% trace metals basis

267112

Sigma-Aldrich

Palladium, wire, diam. 1.0 mm, 99.9% trace metals basis

348678

Sigma-Aldrich

Palladium, foil, thickness 1.0 mm, 99.9% trace metals basis

348643

Sigma-Aldrich

Palladium, foil, thickness 0.25 mm, 99.98% trace metals basis

348694

Sigma-Aldrich

Palladium, wire, diam. 0.5 mm, 99.9% trace metals basis

GF95076625

Palladium, foil, not light tested, 150x150mm, thickness 0.03mm, as rolled, 99.95%

GF16402586

Palladium, foil, not light tested, 25x25mm, thickness 0.002mm, 99.95%

GF36936399

Palladium, foil, light tested, 50x50mm, thickness 0.03mm, as rolled, 99.95%

GF35196330

Palladium, tube, 100mm, outside diameter 2.0mm, inside diameter 1.6mm, wall thickness 0.2mm, as drawn, 99.95%

GF26034230

Palladium, microfoil, disks, 10mm, thinness 0.25μm, specific density 303.4μg/cm², permanent mylar 3.5μm support, 99.99%

GF24288790

Palladium, wire reel, 5m, diameter 0.25mm, hard, 99.95%

GF35916868

Palladium, foil, not light tested, 100x100mm, thickness 0.03mm, as rolled, 99.95%

GF52930762

Palladium, microfoil, disks, 10mm, thinness 0.5μm, specific density 303.4μg/cm², permanent mylar 3.5μm support, 99.99%

GF38967193

Palladium, foil, not light tested, 25x25mm, thickness 0.03mm, as rolled, 99.95%

GF85707513

Palladium, wire reel, 0.5m, diameter 1.0mm, hard, 99.95%

GF12546581

Palladium, wire reel, 0.1m, diameter 0.25mm, hard, 99.95%

GF81435146

Palladium, rod, 100mm, diameter 2.0mm, 99.95%

GF02176332

Palladium, wire reel, 0.2m, diameter 0.5mm, as drawn, 99.95%

GF40398352

Palladium, wire reel, 1m, diameter 0.25mm, hard, 99.95%