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103748

2,3,4,5,6-五氟苯甲醛

Name: 2,3,4,5,6-五氟苯甲醛
Brand: ALDRICH

98%

别名:

Formylpentafluorobenzene, Pentafluorobenzaldehyde

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关于此项目

线性分子式:

C₆F₅CHO

化学文摘社编号:

653-37-2

分子量:

196.07

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24846620

EC Number:

211-502-6

Beilstein/REAXYS Number:

1876550

MDL number:

MFCD00003303

Assay:

98%

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属性

Quality Level

200

assay

98%

refractive index

n20/D 1.45 (lit.)

bp

164-166 °C (lit.)

mp

24-28 °C (lit.)

density

1.588 g/mL at 25 °C (lit.)

functional group

fluoro, aldehyde

SMILES string

Fc1c(F)c(F)c(C=O)c(F)c1F

InChI

1S/C7HF5O/c8-3-2(1-13)4(9)6(11)7(12)5(3)10/h1H

InChI key

QJXCFMJTJYCLFG-UHFFFAOYSA-N

说明

General description

2,3,4,5,6-五氟苯甲醛与 5-（芳基）二吡咯甲烷反应形成各种内消旋-芳基[26]六卟啉。

Application

2,3,4,5,6-五氟苯甲醛用于通过超酸催化含氟羰基化合物的多羟基化反应合成了新型、高分子量的氟化芳香族聚合物。2,3,4,5,6-五氟苯甲醛作为衍生化试剂，采用顶空固相微萃取和气相色谱-串联质谱联用技术，建立了测定污泥中伯胺的灵敏方法。

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H332,H335

pcodes

P261 - P264 - P271 - P302 + P352 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 4 Inhalation - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

170.6 °F - closed cup

flash_point_c

77 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Improved synthesis of meso-aryl-substituted [26]hexaphyrins.

Masaaki Suzuki et al.

Organic letters, 5(21), 3943-3946 (2003-10-11)

[reaction: see text] Acid-catalyzed reactions of 5-(2',3',4',5',6'-pentafluorophenyl)dipyrromethane with aryl aldehydes and of 5-(aryl)dipyrromethanes with 2,3,4,5,6-pentafluorobenzaldehyde allowed the preparation of a variety of meso-aryl [26]hexaphyrins.

A Novel, One-Pot Synthesis of Novel 3F, 5F, and 8F Aromatic Polymers.

Diaz AM, et al.

Macromolecular Rapid Communications, 28(2), 183-187 (2007)

Aminophenyl-substituted cobalt(iii) corrole: a bifunctional electrocatalyst for the oxygen and hydrogen evolution reactions.

Amit Kumar et al.

Dalton transactions (Cambridge, England : 2003), 48(30), 11345-11351 (2019-07-06)

Catalytic water splitting is a highly promising area of research for the development of a hydrogen-based society. Herein, the synthesis of the bifunctional A2B-type cobalt(iii) corrole Co(BAPC)Py2 having the electron-withdrawing meso-pentafluorophenyl and the basic meso-p-aminophenyl substituents is reported. Cyclic voltammetric

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全球贸易项目编号

货号	GTIN
103748-10G	04061838670748
103748-2.5G	04061838670755