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103764

五氟苯磺酰氯

Name: 五氟苯磺酰氯
Brand: ALDRICH

99%

别名:

2,3,4,5,6-Pentafluorophenylsulfonyl chloride, Perfluorobenzenesulfonyl chloride

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关于此项目

线性分子式:

C₆F₅SO₂Cl

化学文摘社编号:

832-53-1

分子量:

266.57

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24846621

EC Number:

212-620-0

Beilstein/REAXYS Number:

2142325

MDL number:

MFCD00007427

Assay:

99%

Form:

solid

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属性

Quality Level

200

assay

99%

form

solid

refractive index

n20/D 1.479 (lit.)

bp

210-211 °C (lit.)

density

1.796 g/mL at 25 °C (lit.)

functional group

fluoro, chloro

SMILES string

Fc1c(F)c(F)c(c(F)c1F)S(Cl)(=O)=O

InChI

1S/C6ClF5O2S/c7-15(13,14)6-4(11)2(9)1(8)3(10)5(6)12

InChI key

UOJCTEGNHXRPKO-UHFFFAOYSA-N

说明

General description

Pentafluorobenzenesulfonyl chloride reacts with benzene and thiophene derivatives in the presence of a ruthenium (II) catalyst to form corresponding perfluorophenylated compounds.

Application

Pentafluorobenzenesulfonyl chloride was used as derivatizing reagent for simultaneous determination of fluoxetine and p-trifluoromethylphenol, an O-dealkylated metabolite of fluoxetine in human liver microsomes. Pentafluorobenzenesulfonyl chloride was used for electrophore labeling of small tyrosyl peptides for their analysis by gas chromatography with electron-capture detection.

Biochem/physiol Actions

Pentafluorobenzenesulfonyl chloride is derivatizing reagent for amphetamine in determination of amphetamine in human plasma samples using gas chromatography with electron-capture detectio.

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 3

flash_point_f

194.0 °F - closed cup

flash_point_c

90 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Pentafluorobenzenesulfonyl chloride: a new electrophoric derivatizing reagent with application to tyrosyl peptide determination by gas chromatography with electron capture detection.

A Sentissi et al.

Analytical chemistry, 56(13), 2512-2517 (1984-11-01)

Perfluorophenylation of aromatic and heteroaromatic compounds with pentafluorobenzenesulfonyl chloride catalyzed by a ruthenium (II) phosphine complex.

Kamigata N, et al.

Journal of Fluorine Chemistry, 87(1), 91-95 (1998)

A rapid method of determining amphetamine in plasma samples using pentafluorobenzenesulfonyl chloride and electron-capture gas chromatography.

S J Asghar et al.

Journal of pharmacological and toxicological methods, 46(2), 111-115 (2002-12-17)

Acute administration of (+)-amphetamine has been used as a model for mania in humans since it mimics the physiological, biochemical, and cognitive effects seen in mania. A rapid and sensitive method for the determination of amphetamine in human plasma samples

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全球贸易项目编号

货号	GTIN
8043120500	04027269069797
H28807-500G	04061833792438
H28807-100G	04061833792421
8043120100	04022536384634
103764-25G	04061837245749
103764-5G	04061837245756