119342
(二甲基氨基甲基)二茂铁
≥95%
别名:
(二茂铁)二甲胺, N,N-二甲基二茂铁甲基胺, 二茂铁甲基胺
质量水平
方案
≥95%
反应适用性
core: iron
reagent type: catalyst
折射率
n20/D 1.59 (lit.)
沸点
124-128 °C/2.5 mmHg (lit.)
密度
1.228 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)C[C]2[CH][CH][CH][CH]2
InChI
1S/C8H12N.C5H5.Fe/c1-9(2)7-8-5-3-4-6-8;1-2-4-5-3-1;/h3-6H,7H2,1-2H3;1-5H;
InChI key
JJJSTEANRWLZBH-UHFFFAOYSA-N
一般描述
二甲基氨基甲基二茂铁(DMAMF)是一种二茂铁，由二甲基氨基甲基取代基连接其中一个配体而成。用作前体制备氧化铁膜。
应用
二甲基氨基甲基二茂铁用于：
- 作为前体通过原子层沉积(ALD)制备氧化铁和镁掺杂氧化铁膜。
- 作为胺配体用于合成五羰基(二甲基氨基甲基二茂铁)钨络合物。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Structural and magnetic studies on iron oxide and iron-magnesium oxide thin films deposited using ferrocene and (dimethylaminomethyl) ferrocene precursors
ECS Journal of Solid State Science and Technology, 2(3), N45-N45 (2012)
Directly fused highly substituted naphthalenes via Pd-catalyzed dehydrogenative annulation of N, N-dimethylaminomethyl ferrocene using a redox process with a substrate
Zhang H, et al.
Organic Letters, 14(12), 3012-3015 (2012)
Yoshihiro Kase et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 20(8), 1143-1146 (2004-09-09)
We propose an electron transfer-mediated amperometric enzyme biosensor based on plasma-polymerized thin film of dimethylaminomethylferrocene (DMAMF) on a sputtered gold electrode. The DMAMF plasma-polymerized film is deposited directly onto the surface of the electrode under dry conditions. The resulting thin
A N Shevel'kova et al.
Biokhimiia (Moscow, Russia), 58(6), 928-937 (1993-06-01)
The effects of dimethylaminomethylferrocene (DMAMF) on amylose and maltodextrins destruction by gluco-, alpha- and beta-amylases have been studied. The nature of DMAMF effects depends on the action mechanism of amylases and structure of their active sites. The effect observed is
[(Dimethylamino)methyl] ferrocene as an Amine Ligand: Study of the Bonding and X-Ray Crystal and Molecular Structure of the Pentacarbonyl{[(dimethylamino)methyl] ferrocene}tungsten Complex
Fischer A, et al.
Collection of Czechoslovak Chemical Communications, 67(2), 228-234 (2002)
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