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Merck
CN

119342

(二甲基氨基甲基)二茂铁

≥95%

别名:

(二茂铁)二甲胺, N,N-二甲基二茂铁甲基胺, 二茂铁甲基胺

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关于此项目

经验公式(希尔记法):
C13H17FeN
化学文摘社编号:
分子量:
243.13
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-044-8
MDL number:
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产品名称

(二甲基氨基甲基)二茂铁, ≥95%

InChI key

JJJSTEANRWLZBH-UHFFFAOYSA-N

InChI

1S/C8H12N.C5H5.Fe/c1-9(2)7-8-5-3-4-6-8;1-2-4-5-3-1;/h3-6H,7H2,1-2H3;1-5H;

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)C[C]2[CH][CH][CH][CH]2

assay

≥95%

reaction suitability

core: iron
reagent type: catalyst

refractive index

n20/D 1.59 (lit.)

bp

124-128 °C/2.5 mmHg (lit.)

density

1.228 g/mL at 25 °C (lit.)

storage temp.

2-8°C

Quality Level

Application

二甲基氨基甲基二茂铁用于:
  • 作为前体通过原子层沉积(ALD)制备氧化铁和镁掺杂氧化铁膜。
  • 作为胺配体用于合成五羰基(二甲基氨基甲基二茂铁)钨络合物。

General description

二甲基氨基甲基二茂铁(DMAMF)是一种二茂铁,由二甲基氨基甲基取代基连接其中一个配体而成。用作前体制备氧化铁膜。

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


历史批次信息供参考:

分析证书(COA)

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A N Shevel'kova et al.
Biokhimiia (Moscow, Russia), 58(6), 928-937 (1993-06-01)
The effects of dimethylaminomethylferrocene (DMAMF) on amylose and maltodextrins destruction by gluco-, alpha- and beta-amylases have been studied. The nature of DMAMF effects depends on the action mechanism of amylases and structure of their active sites. The effect observed is
Yoshihiro Kase et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 20(8), 1143-1146 (2004-09-09)
We propose an electron transfer-mediated amperometric enzyme biosensor based on plasma-polymerized thin film of dimethylaminomethylferrocene (DMAMF) on a sputtered gold electrode. The DMAMF plasma-polymerized film is deposited directly onto the surface of the electrode under dry conditions. The resulting thin
Directly fused highly substituted naphthalenes via Pd-catalyzed dehydrogenative annulation of N, N-dimethylaminomethyl ferrocene using a redox process with a substrate
Zhang H, et al.
Organic Letters, 14(12), 3012-3015 (2012)
Structural and magnetic studies on iron oxide and iron-magnesium oxide thin films deposited using ferrocene and (dimethylaminomethyl) ferrocene precursors
ECS Journal of Solid State Science and Technology, 2(3), N45-N45 (2012)
Guozhen Liu et al.
Analytica chimica acta, 909, 1-8 (2016-02-07)
A stable label-free amperometric immunosensor is presented based on gold nanoparticles and graphene oxide nanocomposites for detection of cardiac troponin-I in the early diagnosis of myocardial infarction. For designing of the sensing platform, firstly the nanocomposites based on GO and

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