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Merck
CN

14814

氯化钯(II)

anhydrous, 59-60% Pd, powder

别名:

Dichloropalladium, Palladium dichloride, Palladous chloride

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关于此项目

经验公式(希尔记法):
Cl2Pd
化学文摘社编号:
分子量:
177.33
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
231-596-2
MDL number:
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产品名称

氯化钯(II), anhydrous, 59-60% palladium (Pd) basis

Quality Level

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

concentration

59-60% Pd

mp

678-680 °C (lit.)

density

4 g/mL at 25 °C (lit.)

SMILES string

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

InChI key

PIBWKRNGBLPSSY-UHFFFAOYSA-L

Application

钯催化交叉偶联反应的应用指南

用于合成含半导体金属的聚合物,其中聚吡咯骨架具有最小构象能并且几乎是平面的。
Palladium catalysts and precursor used as an oxidizing agent and as a source of Pd(0) complexes.


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signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

存储类别

13 - Non Combustible Solids

法规信息

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分析证书(COA)

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Rui Yang et al.
ChemSusChem, 13(10), 2621-2627 (2020-02-11)
Metal-CO2 batteries, an attractive technology for both energy storage and CO2 utilization, are typically classified into organic Li(Na)-CO2 batteries with a high energy density/output voltage and aqueous Zn-CO2 batteries with flexible chemical production. However, achieving both high-efficiency energy storage and
Maozhong Miao et al.
Organic letters, 14(11), 2718-2721 (2012-05-16)
A novel PdCl(2)-catalyzed oxidative cycloisomerization of 3-cyclopropylideneprop-2-en-1-ones, providing a facile synthesis of highly strained functionalized 2-alkylidenecyclobutanones via furan-fused cyclobutene intermediates, is reported. An interesting route to 2(3H)-furanones with a spiro-cyclopropane unit from the obtained 2-alkylidenecyclobutanones via a ring-contraction rearrangement reaction
Yves Canac et al.
Inorganic chemistry, 50(21), 10810-10819 (2011-10-11)
The influence of the formal electrostatic interaction on the cis/trans coordination mode at a PdCl(2) center is investigated in a family of isostructural flexible diphosphine ligands Ph(2)P-X-C(6)H(4)-Y-PPh(2), where X and Y stand for neutral or cationic N,C-imidazolylene linkers. While the



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货号GTIN
14814-10G04061833472699