160512
氯甲酸-9-芴基甲酯
97%, for peptide synthesis
别名:
9-芴甲氧羰酰氯, Fmoc-Cl, 芴甲氧羰酰氯
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关于此项目
经验公式（希尔记法）:
C15H11ClO2
化学文摘社编号:
分子量:
258.70
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352108
EC Number:
249-313-6
MDL number:
Beilstein/REAXYS Number:
2279177
产品名称
氯甲酸-9-芴基甲酯, 97%
InChI key
IRXSLJNXXZKURP-UHFFFAOYSA-N
InChI
1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2
SMILES string
ClC(=O)OCC1c2ccccc2-c3ccccc13
assay
97%
form
solid
mp
62-64 °C (lit.)
application(s)
peptide synthesis
functional group
Fmoc
chloro
storage temp.
2-8°C
Quality Level
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Application
在氨基酸 HPLC 分析中，用于衍生化氨基酸；在固相肽合成中用于制备 N-Fmoc 氨基酸。
氨基保护试剂，最近用于合成二环脯氨酸类似物。
用于HPLC分析的氨基酸衍生物。用于多肽和寡核苷酸合成的N端保护试剂。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Helvetica Chimica Acta, 75, 1111-1111 (1992)
Journal of the Chemical Society. Chemical Communications, 369-369 (1993)
Jae Hyun Kim et al.
Nanomaterials (Basel, Switzerland), 11(1) (2020-12-31)
Here, we report a post-synthesis functionalization of the shell of Au nanoclusters (NCs) synthesized using glutathione as a thiolate ligand. The as-synthesized Au NCs are subjected to the post-synthesis functionalization via amidic coupling of dopamine on the cluster shell to
Brett H Pogostin et al.
Molecules (Basel, Switzerland), 24(3) (2019-01-27)
Determining the pKa of key functional groups is critical to understanding the pH-dependent behavior of biological proteins and peptide-based biomaterials. Traditionally, ¹H NMR spectroscopy has been used to determine the pKa of amino acids; however, for larger molecules and aggregating
F Lai et al.
BioTechniques, 14(4), 642-649 (1993-04-01)
Pre-column derivatizations of amino acids often present two major challenges: 1) automation, due to the multi-step manipulations for pH control, reagent addition, mixing and extraction, and 2) effect of matrices in the sample such as salts, buffers and surfactants. Both
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