164100
乙酰乙酸乙酯 钠盐
别名:
乙基乙酰乙酸钠, 乙基钠代乙酰乙酸, 乙酰乙酸乙酯钠
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线性分子式:
CH3C(ONa)=CHCO2C2H5
化学文摘社编号:
分子量:
152.12
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
方案
90-110% (perchloric acid titration)
表单
powder, crystals or chunks
反应适用性
core: sodium
杂质
≤10% Acetic acid sodium salt
mp
168 °C (dec.) (lit.)
储存温度
2-8°C
SMILES字符串
[Na+].CCOC(=O)\C=C(/C)[O-]
InChI
1S/C6H10O3.Na/c1-3-9-6(8)4-5(2)7;/h4,7H,3H2,1-2H3;/q;+1/p-1/b5-4+;
InChI key
RYLPINAPVLRJBZ-FXRZFVDSSA-M
一般描述
Ethyl acetoacetate sodium salt is an organic compound typically appearing as a white to yellow to beige solid. It is used as a precursor or additive in the fabrication of functional organic-inorganic hybrid materials. It is also employed in the synthesis of advanced electrode materials, such as metal oxide nanoparticles, by acting as a stabilizer or precursor in solution-phase reactions. Its applications extend to areas like fuel cells, batteries, and supercapacitors, where it can play a role in the preparation of complex materials and doping processes.
应用
Ethyl acetoacetate sodium salt can be used as:
- A chelating agent or ligand precursor to form metal-organic frameworks (MOFs) and coordination polymers, which are important in catalysis, sensors, and energy storage materials.
- A stabilizer or precursor in solution-phase reactions to produce metal oxide nanoparticles, which serve as advanced electrode materials in batteries, supercapacitors, and fuel cells.
- A β-keto ester component in the synthesis of complex heterocyclic structures, which are of significant interest in medicinal chemistry.
储存分类代码
11 - Combustible Solids
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Ethyl acetoacetate and acetylacetone appended hexabromo porphyrins: synthesis, spectral, electrochemical, and femtosecond third-order nonlinear optical studies
Rohal, Renu Kumari and Banerjee, et al.
Dalton Transactions, 52, 5523-5533 (2023)
Michael addition of ethyl acetoacetate on dibenzylideneacetone derivatives: Synthesis, spectroscopy, antimicrobial and in silico studies
Mouhib, Ayoub and Es-Sounni, et al.
Journal of Molecular Structure, 1321, 139790-139790 (2025)
Improvement of the Ethyl Acetoacetate Preparation Experiment: A Green Chemistry Experiment
Tan, Da-Zhi and Li, Ming-Ze and Xiong, et al.
Journal of Chemical Education, 100, 811-814 (2023)
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