171565
苯基溴化镁 溶液
3.0 M in diethyl ether
别名:
Bromomagnesiobenzene, Bromophenylmagnesium
登录 查看组织和合同定价。
选择规格
变更视图
关于此项目
线性分子式:
C6H5MgBr
化学文摘社编号:
分子量:
181.31
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3588849
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Kilo-Lab® of , Sure/Seal™ of
concentration
3.0 M in diethyl ether
density
1.134 g/mL at 25 °C
SMILES string
Br[Mg]c1ccccc1
InChI
1S/C6H5.BrH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key
ANRQGKOBLBYXFM-UHFFFAOYSA-M
General description
Phenylmagnesium bromide solution contains 3M phenylmagnesium bromide in diethyl ether. It can act as a strong acid and Lewis acid. It can undergo addition reaction with many unsaturated functional groups. The phenyl group can displace halide from other organic compounds. Phenylmagnesium bromide is a Grignard reagent. Reaction of β-cyclohexanedione (dihydroresorcinol) with phenylmagnesium bromide has been investigated.
Application
Phenylmagnesium bromide was used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It was also used for the monoalkylation of aliphatic primary amine to generate secondary amines by the Grignard reaction of 1-[(alkylamino) methyl] benzotriazoles.
It may be used for synthesis of the following:
It may be used for synthesis of the following:
- 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol
- 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol
- (3-(2-Dithiobenzoatepropionyl)propyl)dimethylmethoxysilane, reversible addition-fragmentation chain transfer polymerization (RAFT)-silane agent
- series of o-substituted benzophenones
Packaging
Other Notes
储存温度低于 25°C 可能形成结晶镁盐。将容器移至温暖处不时温和搅拌可使固体重新溶解
Legal Information
Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
Still not finding the right product?
Explore all of our products under 苯基溴化镁 溶液
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-40.0 °F - closed cup
flash_point_c
-40 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter