189901
甲基氯化镁 溶液
3.0 M in THF
别名:
Chloromethylmagnesium, Methyl magnesium chloride, Methylmagnesiumchloride
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关于此项目
线性分子式:
CH3MgCl
化学文摘社编号:
分子量:
74.79
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587199
Concentration:
3.0 M in THF
Form:
liquid
form
liquid
Quality Level
autoignition temp.
609 °F
reaction suitability
reaction type: Grignard Reaction
packaging
Kilo-Lab® of , Sure/Seal™ of
concentration
3.0 M in THF
density
1.013 g/mL at 25 °C
SMILES string
C[Mg]Cl
InChI
1S/CH3.ClH.Mg/h1H3;1H;/q;;+1/p-1
InChI key
RQNMYNYHBQQZSP-UHFFFAOYSA-M
Application
将甲基氯化镁溶液（3M，溶于THF中）用二醛糖衍生的硝酮进行1,3-加成反应，可形成 N-苄基羟胺。通过这些N-苄基羟胺的N-O键的还原裂解，可产生N-苄氨基糖，其是生物活性化合物的关键基团。它还可以与Garner型醛反应形成相应的仲醇。
Legal Information
Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
1.0 °F - closed cup
flash_point_c
-17.2 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
法规信息
危险化学品
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商品
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
A new route to aminosugars from sugar nitrones: synthesis of 6-deoxynojirimycin.
Dhavale DD
Tetrahedron Asymmetry, 8(9), 1475-1486 (1997)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 189901-18L-C | 04061837789755 |
| 189901-8L | 04061837789779 |
| 189901-18L-KL | 04061837789762 |
| 189901-PZ | 04061823808323 |
| 189901-4X25ML | 04061838759504 |
| 189901-100ML | 04061838759498 |
| 189901-800ML | 04061838759511 |