196215
双(环戊二烯基)二氯化锆(IV)
≥98%, solid
别名:
二氯二茂, 二氯化双环戊二烯锆, 二氯双环戊二烯锆, 二(环戊二烯基)二氯化锆(IV), 二氯二茂锆
产品名称
双(环戊二烯基)二氯化锆(IV), ≥98%
方案
≥98%
表单
solid
反应适用性
core: zirconium
reaction type: Polymerization Reactions
reagent type: catalyst
reaction type: Olefin Metathesis
环保替代产品特性
Catalysis
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参数
moisture sensitive
mp
242-245 °C (lit.)
环保替代产品分类
, Aligned
储存温度
2-8°C
SMILES字符串
Cl[Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.2ClH.Zr/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key
QRUYYSPCOGSZGQ-UHFFFAOYSA-L
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一般描述
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了催化效率。详细信息见于此处。
二氯二茂锆可用作催化剂，从而实现吡咯的高效催化，产率高，简化纯化过程。
二氯二茂锆可用作催化剂，从而实现吡咯的高效催化，产率高，简化纯化过程。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
Benjamin N Atkinson et al.
Chemical communications (Cambridge, England), 48(95), 11626-11628 (2012-10-26)
Zirconocene dichloride (Cp(2)ZrCl(2)) has been shown to be an effective catalyst for the transamidation of primary amides with amines in cyclohexane at 80 °C in 5-24 hours. For favourable substrates, the reaction can be performed at temperatures as low as
Aldrichimica Acta, 17, 28-28 (1984)
Anita Lagutschenkov et al.
The journal of physical chemistry. A, 114(5), 2073-2079 (2010-01-21)
Cationic zirconocene complexes are active species in Ziegler-Natta catalysis for olefin polymerization. Their structure and metal-ligand bond strength strongly influence their activity. In the present work, the infrared multiphoton dissociation (IRMPD) spectrum of mass selected Zr(C(5)H(5))(2)(OH)(CH(3)CN)(+) cations was obtained in
Zirconocene dichloride catalysed one-pot synthesis of pyrroles through nitroalkene-enamine assembly
Goyal S, et al.
Royal Society of Chemistry Advances, 5, 3187-3195 (2015)
Vidar R Jensen et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 6(9), 1929-1933 (2005-08-03)
Free Car-Parrinello molecular dynamics (CPMD) simulations of four diastereomers of the zirconium-propene complexes [{iPr(3-iPr-CpFlu)}ZriBu(C3H6)]+ (Cp=cyclopentadienyl; Flu=fluorenyl) provide valuable insight into the mechanism and stereocontrol of propene polymerization with stereorigid metallocenes. Spontaneous insertion of propene into the zirconium-isobutyl bond is not
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