196789
2,3,5,6-四氟苯酚
97%
别名:
1,2,4,5-四氟-3-羟基苯
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关于此项目
线性分子式:
HC6F4OH
化学文摘社编号:
分子量:
166.07
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
212-209-6
MDL number:
产品名称
2,3,5,6-四氟苯酚, 97%
InChI key
PBYIIRLNRCVTMQ-UHFFFAOYSA-N
InChI
1S/C6H2F4O/c7-2-1-3(8)5(10)6(11)4(2)9/h1,11H
SMILES string
Oc1c(F)c(F)cc(F)c1F
assay
97%
form
solid
bp
140 °C (lit.)
mp
37-39 °C (lit.)
functional group
fluoro
Quality Level
Application
2,3,5,6-四氟苯酚用于制备：
- 在肽合成中有用的放射性碘标记苯丙氨酸衍生物
- 锝-99m 标记抗体
hcodes
signalword
Warning
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
dust mask type N95 (US), Eyeshields, Gloves
K Detmer et al.
The Journal of biological chemistry, 260(10), 5998-6005 (1985-05-25)
The oxidative half-reaction of phenol hydroxylase has been studied by stopped-flow spectrophotometry. Three flavin-oxygen intermediates can be detected when the substrate is thiophenol, or m-NH2, m-OH, m-CH3, m-Cl, or p-OH phenol. Intermediate I, the flavin C(4a)-hydroperoxide, has an absorbance maximum
A R Fritzberg et al.
Proceedings of the National Academy of Sciences of the United States of America, 85(11), 4025-4029 (1988-06-01)
Technetium-99m labeling of antibodies has been suboptimal because of low affinity adventitious binding, nonspecific labeling, and loss of immunoreactivity. The diamide dithiolate ligand system (N2S2) forms highly stable, well-defined tetradentate complexes with Tc(V). Antibodies and their fragments have been labeled
D S Wilbur et al.
Bioconjugate chemistry, 4(6), 574-580 (1993-11-01)
An investigation to prepare a phenylalanine derivative which could be radioiodinated and used directly in peptide synthesis was conducted. N-Boc-p-(tri-n-butylstannyl)-L-phenylalanine tetrafluorophenyl ester was targeted and synthesized from N-Boc-p-iodo-L-phenylalanine. The requisite aryl stannylation reaction was found to be best conducted using
Vijay Gaja et al.
Molecules (Basel, Switzerland), 25(11) (2020-06-11)
The increased interest in 89Zr-labelled immunoPET imaging probes for use in preclinical and clinical studies has led to a rising demand for the isotope. The highly penetrating 511 and 909 keV photons emitted by 89Zr deliver an undesirably high radiation
C den Besten et al.
Chemical research in toxicology, 6(5), 674-680 (1993-09-01)
In the present study the oxidative dehalogenation of a para-halogenated phenol was studied using pentafluorophenol and its non-para-halogenated analogue 2,3,5,6-tetrafluorophenol as model compounds. 19F NMR was used to characterize the metabolite patterns. In order to study the primary oxidation products
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