206113
氯化铂(IV)
96%
别名:
四氯化铂
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关于此项目
线性分子式:
PtCl4
化学文摘社编号:
分子量:
336.89
EC 号:
MDL编号:
UNSPSC代码:
12352302
eCl@ss:
38191307
PubChem化学物质编号:
NACRES:
NA.23
方案
96%
表单
powder and chunks
反应适用性
core: platinum
reagent type: catalyst
mp
370 °C (dec.) (lit.)
密度
4.303 g/mL at 25 °C (lit.)
应用
PEM fuel cells
homogeneous catalyst
material synthesis precursor
SMILES字符串
Cl[Pt](Cl)(Cl)Cl
InChI
1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4
InChI key
FBEIPJNQGITEBL-UHFFFAOYSA-J
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应用
氯化铂(IV) 可作为前体用于合成各种有机转化反应中的铂基催化剂。例如，碳载铂-钌纳米颗粒可用作甲醇和乙醇氧化的高效催化剂。
由于其对糖基受体羟基的高亲和力和双齿配体结合能力，它可用作区域和立体选择性糖苷化反应的双功能催化剂。
它也可用于TiO2 的光敏化和表面修饰，从而实现4-氯苯酚的光降解。
由于其对糖基受体羟基的高亲和力和双齿配体结合能力，它可用作区域和立体选择性糖苷化反应的双功能催化剂。
它也可用于TiO2 的光敏化和表面修饰，从而实现4-氯苯酚的光降解。
警示用语：
Danger
危险分类
Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 2
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Agnieszka Jańczyk et al.
Journal of photochemistry and photobiology. B, Biology, 92(1), 54-58 (2008-06-17)
Phototoxicity of titanium dioxide modified with platinum(IV)-chloride complexes, [TiO2/PtCl4], irradiated with visible light was tested on murine macrophage cell line (RAW 264.7) in vitro. Presence of antioxidants such as alpha-tocopherol or beta-carotene during photodynamic treatment significantly increased cells viability. Our
The mutagenic effect of platinum compounds in Drosophila melanogaster.
R C Woodruff et al.
Environmental mutagenesis, 2(2), 133-138 (1980-01-01)
A P Boswell et al.
The Biochemical journal, 201(3), 523-526 (1982-03-01)
The binding of [PtCl4]2- and cis-[PtCl2(NH3)2] to methionine-65 of tuna cytochrome c was investigated by 1H n.m.r. The modification at methionine-65 is shown to cause an extremely small structural perturbation to the protein at the site of modification.
Jochen Autschbach et al.
Magnetic resonance in chemistry : MRC, 46 Suppl 1, S45-S55 (2008-10-16)
Pt chemical shifts were calculated from two-component relativistic density functional theory (DFT). The shielding tensors were analyzed by using a recently developed method to decompose the spin-orbit DFT results into contributions from spin-free localized orbitals (here: natural localized molecular orbitals
PtCl4-catalyzed domino synthesis of fused bicyclic acetals.
Alejandro Diéguez-Vázquez et al.
Angewandte Chemie (International ed. in English), 47(1), 209-212 (2007-12-07)
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