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Merck
CN

206113

氯化铂(IV)

96%

别名:

四氯化铂

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关于此项目

线性分子式:
PtCl4
化学文摘社编号:
分子量:
336.89
PubChem Substance ID:
eCl@ss:
38191307
UNSPSC Code:
12352302
NACRES:
NA.23
EC Number:
236-645-1
MDL number:
Assay:
96%
Form:
powder and chunks
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Quality Level

assay

96%

form

powder and chunks

reaction suitability

core: platinum, reagent type: catalyst

mp

370 °C (dec.) (lit.)

density

4.303 g/mL at 25 °C (lit.)

application(s)

PEM fuel cells
homogeneous catalyst
material synthesis precursor

SMILES string

Cl[Pt](Cl)(Cl)Cl

InChI

1S/4ClH.Pt/h4*1H;/q;;;;+4/p-4

InChI key

FBEIPJNQGITEBL-UHFFFAOYSA-J

Application

氯化铂(IV) 可作为前体用于合成各种有机转化反应中的铂基催化剂。例如,碳载铂-钌纳米颗粒可用作甲醇和乙醇氧化的高效催化剂。

由于其对糖基受体羟基的高亲和力和双齿配体结合能力,它可用作区域和立体选择性糖苷化反应的双功能催化剂。

它也可用于TiO2 的光敏化和表面修饰,从而实现4-氯苯酚的光降解。


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signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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PtCl4-catalyzed domino synthesis of fused bicyclic acetals.
Alejandro Diéguez-Vázquez et al.
Angewandte Chemie (International ed. in English), 47(1), 209-212 (2007-12-07)
Barbora Nemcova et al.
Neuro endocrinology letters, 33 Suppl 3, 173-178 (2013-01-29)
Regarding the environmental pollution, platinum group elements (PGE) are in the centre of interest of current research. These rare elements are used as effective substances in automotive catalysts to reduce pollution by emissions originating from fuel combustion. Due to their
Agnieszka Jańczyk et al.
Journal of photochemistry and photobiology. B, Biology, 92(1), 54-58 (2008-06-17)
Phototoxicity of titanium dioxide modified with platinum(IV)-chloride complexes, [TiO2/PtCl4], irradiated with visible light was tested on murine macrophage cell line (RAW 264.7) in vitro. Presence of antioxidants such as alpha-tocopherol or beta-carotene during photodynamic treatment significantly increased cells viability. Our



全球贸易项目编号

货号GTIN
206113-5G04061838768476
206113-1G04061838342898
206113-250MG04061838768469