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文件

206229

Sigma-Aldrich

氯化钌 (III) 水合物

ReagentPlus®

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别名:
三氯化钌
线性分子式:
RuCl3 · xH2O
CAS号:
14898-67-0
分子量:
207.43 (anhydrous basis)
EC 号:
233-167-5
MDL编号:
MFCD00149844
PubChem化学物质编号:
24852386
NACRES:
NA.23

产品线

ReagentPlus®

形式

powder and chunks

组成

Degree of hydration, ≤1
Ruthenium content, 40.00-49.00%

反应适用性

reagent type: catalyst
core: ruthenium

杂质

≤0.1% Insoluble matter (C=1%, 25% HCl)

SMILES字符串

O.Cl[Ru](Cl)Cl

InChI

1S/3ClH.H2O.Ru/h3*1H;1H2;/q;;;;+3/p-3

InChI key

BIXNGBXQRRXPLM-UHFFFAOYSA-K

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相关类别

一般描述

可溶型

应用

它被用于制备纳米颗粒钌-氢氧化铝氧化物催化剂，使芳甲基醇有效脱氢生成相应的醛。该产物可催化由伯芳香胺和三烯丙基胺合成2-乙基-3-甲基喹啉。使用 RhCl3 在二氧化钛纳米管上沉积制备的钌水合氧化物，可用作分子氧选择性氧化醇的催化体系。

法律信息

ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany

警示用语：

Danger

危险声明

H302 - H314 - H411

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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TiO 2 nanotube-supported ruthenium (III) hydrated oxide: A highly active catalyst for selective oxidation of alcohols by oxygen.
Bavykin DV, et al.
J. Catal., 235(1), 10-17 (2005)
Cho, C.S. et al.
Tetrahedron Letters, 40, 1499-1499 (1999)
Won-Hee Kim et al.
Organic letters, 8(12), 2543-2545 (2006-06-02)
An efficient oxidant-free oxidation for a wide range of alcohols was achieved by a recyclable ruthenium catalyst. The catalyst was prepared from readily available reagents by a one-pot synthesis through nanoparticle generation and gelation. [structure: see text]
Yao Zhang et al.
European journal of medicinal chemistry, 86, 449-455 (2014-09-10)
Ruthenium-based anticancer complexes have become increasingly popular for study over the last two decades. Although ruthenium complexes are currently being investigated in clinical trials, there are still some difficulties with their delivery and associated side effects. Human serum albumin (HSA)-based
Huaiyi Huang et al.
Dalton transactions (Cambridge, England : 2003), 44(35), 15602-15610 (2015-08-08)
Ruthenium complexes have been considered as promising substitutes for cisplatin in cancer chemotherapy. However, novel ruthenium-based therapies are faced with some limitations, such as unimpressive cytotoxicity toward solid tumors. Herein, we designed and synthesized phenyl-substituted terpyridyl ruthenium(ii) complexes ([Ru(tpy)(bpy)Cl](+) (Ru1)
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