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Merck
CN

208248

乙酰丙酮铝

98%

别名:

2,4-乙酰丙酮铝, Al(acac)3

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关于此项目

线性分子式:
Al(C5H7O2)3
化学文摘社编号:
13963-57-0
分子量:
324.31
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
24852500
EC Number:
237-741-6
Beilstein/REAXYS Number:
4157942
MDL number:
MFCD00000013

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InChI key

KILURZWTCGSYRE-LNTINUHCSA-K

InChI

1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

SMILES string

CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

assay

98%

form

solid

reaction suitability

core: aluminum

bp

315 °C (lit.)

mp

190-193 °C (lit.)

Quality Level

200

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General description

乙酰丙酮铝不溶于水，但可溶于有机溶剂。在高温下与碱、酸、水反应。它可以通过 AlCl3 与乙酰丙酮反应制备。

Application

乙酰丙酮铝可用于：
  • 升华法制备透明超疏水的薄水铝石和二氧化硅薄膜，
  • 化学气相沉积氧化铝薄膜，
  • 作为催化剂。

pictograms

Skull and crossbones
GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

244.4 °F

flash_point_c

118 °C

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCZ3897
MKCZ3899
MKCZ3898
MKCZ3203
MKCW9572

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Preparation of transparent superhydrophobic boehmite and silica films by sublimation of aluminum acetylacetonate.
Nakajima A, et al.
Advanced Mat., 11(16), 1365-1368 (1999)
Aluminum oxide thin films prepared by chemical vapor deposition from aluminum acetylacetonate
Maruyama T, et al.
Applied Physics Letters, 60(3), 322-323 (1992)
G G Bombi et al.
Environmental health perspectives, 89, 217-223 (1990-11-01)
Aluminum lactate [Al(lact)3] (hydrophilic, hydrolytically unstable) and aluminum acetylacetonate [Al(acae)3] (lipophilic, hydrolytically stable) were tested as potential toxicants to rabbits upon IV administration both as aqueous solutions and as liposome suspensions. Both chemicals behaved as cardiotoxic agents when administered as
P Zatta et al.
Journal of inorganic biochemistry, 65(2), 109-114 (1997-02-01)
The action of aluminum [Al(III)] as Al(acac)3 on erythrocytes causes biophysical effects such as osmotic fragility and echino-acanthocytes formation. In this paper, we present these effects in terms of variation of membrane fluidity, together with findings regarding conformational modifications of
P Zatta et al.
Toxicology letters, 45(1), 15-21 (1989-01-01)
Tris acetylacetonate aluminium(III) (Al(acac)3), dissolved in water, is effective in producing osmotic fragility in suspended erythrocytes in the concentration range of 0.034-0.34 mmol/l. Water solutions of Tris maltolate aluminium(III) (Al(malt)3) and aluminium lactate (Al(lac)3) are also effective but the dose-response
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