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Merck
CN

221678

Raney®-镍

W.R. Grace and Co. Raney® 2800, slurry, in H2O, active catalyst

别名:

雷尼镍, 海绵镍

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关于此项目

线性分子式:
AlNi
化学文摘社编号:
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
MDL number:
eCl@ss:
38190701
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Quality Level

form

slurry

composition

Ni, ≥89%

reaction suitability

core: nickel, reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney® 2800

concentration

in H2O

impurities

6-9% Al

particle size

20-60 μm

pH

8.5-12.0

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

Application

用作有机化合物氢化作用的还原剂,如腈氢化成胺、芳基还原成相应的饱和化合物、β-酮酸酯加氢反应、还原胺化,还用于羟吲哚与醇的3-烷基化反应、Ullman型交叉偶联反应和脱卤反应。
适于用作芳基、烯基、氰基和硝基还原的加氢催化剂。

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.


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signalword

Danger

Hazard Classifications

Carc. 2 - Pyr. Liq. 1 - Skin Sens. 1 - STOT RE 1

存储类别

4.2 - Pyrophoric and self-heating hazardous materials

wgk

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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商品

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.


Michał Sarul et al.
Advances in clinical and experimental medicine : official organ Wroclaw Medical University, 22(2), 253-260 (2013-05-28)
Cognizance of the mechanical properties of nickel-titanium archwires is necessary for the management of orthodontic therapy with fixed appliances. Acting on the periodontium with forces that are too heavy may lead to such complications as: pain, tooth root resorption and
A J Feilzer et al.
Nederlands tijdschrift voor tandheelkunde, 120(6), 335-341 (2013-07-19)
Orally applied metal alloys can cause undesirable physical effects. A distinction needs to be made in this respect between local and systemic reactions and toxic and immunological reactions. A case is presented which illustrates this problem. In this case, the
Palatally anchored maxillary molar mesialization using the mesialslider.
Benedict Wilmes et al.
Journal of clinical orthodontics : JCO, 47(3), 172-179 (2013-05-11)



全球贸易项目编号

货号GTIN
221678-100G04061838777478
221678-500G04061835554591