223670
双(环戊二烯基)氢氯化锆(IV)
95%
别名:
Schwartz 试剂, 二(环戊二烯基)氢氯化锆(IV), 氢氯二茂锆
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关于此项目
经验公式（希尔记法）:
C10H11ClZr
化学文摘社编号:
分子量:
257.87
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352101
EC Number:
253-479-5
MDL number:
Quality Level
assay
95%
form
powder
reaction suitability
core: zirconium, reagent type: catalyst, reagent type: reductant
SMILES string
[H][Zr]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.ClH.Zr.H/c2*1-2-4-5-3-1;;;/h2*1-5H;1H;;/q;;;+1;/p-1
InChI key
PSYHEBZUPSHSKK-UHFFFAOYSA-M
General description
双（环戊二烯）二氯氢化锆′，也称为Schwartz试剂，可用作烯烃聚合的催化剂。
Application
使用双（环戊二烯基）氯化锆氢化物(IV)：
- 将酰胺转化为醛。
- 用作烯烃和炔烃的功能化试剂。
- 作为还原剂制备(E)- 乙烯有机硫属化合物。
- 制备二氧硼戊环衍生物，这是合成桥联尼古丁类似物的关键中间体。
signalword
Danger
hcodes
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Skin Corr. 1B - Water-react. 2
Preparation, characterization, and activity of silica supported metallocene catalysts
L Britcher, et al.
Chemistry of Materials, 16, 5713-5720 (2004)
Bruce Ganem et al.
The Journal of organic chemistry, 72(11), 3981-3987 (2007-03-27)
In this Perspective, which describes the achievements recognized by the 2007 ACS Award for Creative Invention, we discuss the discovery of a new synthetic reaction and its translation into a substantially improved method for manufacturing a major pharmaceutical product--the blockbuster
Organic Syntheses, 71, 83-83 (1992)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 223670-5G | 04061838778635 |
| 223670-1G | 04061826732106 |
| 223670-25G | 04061833545331 |