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Merck
CN

223689

二(氰基苯)二氯化钯(II)

greener alternative

95%, powder

别名:

二(氰基苯)二氯化钯(II), 二氯化钯双（苯甲腈）, 二氯双（苯甲腈）钯, 二氯双（苯甲腈）钯 (II), 二苯甲腈二氯化钯, 双（苯甲腈）二氯化钯 (II), 双（苯腈）二氯化钯, 氯化钯(II)双(苄腈)络合物, 苯甲腈钯络合物

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关于此项目

线性分子式:
(C6H5CN)2PdCl2
化学文摘社编号:
14220-64-5
分子量:
383.57
NACRES:
NA.22
PubChem Substance ID:
24853396
UNSPSC Code:
12161600
EC Number:
238-085-3
MDL number:
MFCD00013123
Beilstein/REAXYS Number:
3981730

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产品名称

二(氰基苯)二氯化钯(II), 95%

InChI key

WXNOJTUTEXAZLD-UHFFFAOYSA-L

InChI

1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

SMILES string

Cl[Pd]Cl.N#Cc1ccccc1.N#Cc2ccccc2

assay

95%

form

powder

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

greener alternative product characteristics

Catalysis
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sustainability

Greener Alternative Product

mp

131 °C (lit.)

greener alternative category

Aligned,

Quality Level

100

相关类别

General description

二（苯腈）氯化钯（II）是一咱种配位化合物，在Suzuki交叉偶联反应中用作催化剂。


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Application

双（笨腈）氯化钯（II）可作为催化剂，用于：
  • 通过 Wacker 氧化，从末端烯烃更绿色环保地合成胺，然后转移氢化所得亚胺。
  • 交叉偶联反应 和 α-O-糖苷化。

末端烯烃的正式反马氏氢胺化反应

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCW3273
MKCW0545
0000315504
0000315504
MKCV6486

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Wei Shi et al.
Chemical communications (Cambridge, England), (23), 2342-2344 (2007-09-12)
A direct alkynylation of readily available alpha-halo esters and amides with high yields is described herein; a distinct switch from diyne formation to alkynylation products was attained under neutral conditions.
Catalysts of Suzuki Cross-Coupling Based on Functionalized Hyper-cross-linked Polystyrene: Influence of Precursor Nature
Nemygina N, et al.
Organic Process Research & Development, 20(8), 1453-1460 (2019)
Brandon P Schuff et al.
Organic letters, 9(16), 3173-3176 (2007-07-10)
A novel method for palladium-catalyzed stereoselective formation of alpha-O-glycosides has been developed. This strategy relies on the palladium-biaryl phosphine catalyst-glycal donor complexation to control the anomeric selectivity. It does not depend on the nature of the protecting groups on the
Synthesis, 803-803 (1992)
Shih-Chieh Yeh et al.
Polymers, 11(12) (2019-12-11)
A crucial polymer intermediate, 4-[1-(4-hydroxyphenyl)cyclopentyl]-phenol (bisphenol CP), was developed from dicyclopentadiene (DCPD), a key byproduct of the C5 fraction in petrochemicals. On the basis of bisphenol CP, a diamine, 4,4'-((cyclopentane-1,1-diylbis(4,1-phenylene))bis(oxy))-dianiline (cyclopentyl diamine; CPDA) was subsequently obtained through a nucleophilic substitution

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