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线性分子式:
Li2CuCl4
化学文摘社编号:
分子量:
219.24
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352302
EC Number:
203-726-8
MDL number:
Form:
liquid
产品名称
四氯合铜酸二锂(II) 溶液, 0.1 M in THF
InChI key
HCJWWBBBSCXJMS-UHFFFAOYSA-J
InChI
1S/4ClH.Cu.2Li/h4*1H;;;/q;;;;+2;2*+1/p-4
SMILES string
[Li+].[Li+].Cl[Cu--](Cl)(Cl)Cl
form
liquid
reaction suitability
reagent type: catalyst
concentration
0.1 M in THF
density
0.91 g/mL at 25 °C
application(s)
battery precursors
catalysts
material synthesis precursor
Quality Level
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Application
用于卤代烷与烷基格氏试剂偶联反应的催化剂。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Kenji Mori
Bioscience, biotechnology, and biochemistry, 74(3), 595-600 (2010-03-09)
A mixture of the four stereoisomers of 1,7-dimethylnonyl propanoate, the female sex pheromone of the western corn rootworm (Diabrotica virgifera virgifera LeConte), was synthesized in four different ways by employing one of the following four reactions as the key step:
K Minamoto et al.
Nucleic acids symposium series, (27)(27), 109-110 (1992-01-01)
The reaction of 1-(2,3-anhydro-5-O-trityl-beta-D-lyxofuranosyl)-2-O-methyluracil (1a) and its thymine analogue (1b) with dilithium tetrahalocuprate (Li2CuX4) revealed excellent to perfect regioselectivity, yielding 2,2'-anhydro-3'-halonucleosides (2a-d), while the same reactions with 2,3-anhydro uracil and thymine nucleosides (4a,b) gave arabinosyl (5a-d) and xylosyl halohydrins (6a-d)
Tetrahedron, 62, 4851-4851 (2006)
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