224421
仲丁基氯化镁 溶液
2.0 M in diethyl ether
别名:
2-Butylmagnesium chloride, Chloro(1-methylpropyl)magnesium, sec-Butylchloromagnesium
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关于此项目
线性分子式:
CH3CH2CH(CH3)MgCl
化学文摘社编号:
分子量:
116.87
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3600265
Concentration:
2.0 M in diethyl ether
InChI
1S/C4H9.ClH.Mg/c1-3-4-2;;/h3H,4H2,1-2H3;1H;/q;;+1/p-1
SMILES string
CCC(C)[Mg]Cl
InChI key
MJHZUYZQMNONPK-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in diethyl ether
density
0.828 g/mL at 25 °C
Quality Level
Application
sec-Butylmagnesium chloride solution is a Grignard reagent, it can be used in:
- Metal catalyzed cross-coupling reactions with non-activated aryl chlorides.
- The synthesis of various alkoxytrichlorosilanes by reacting with tetrachlorosilane and alcohols.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
target_organs
Central nervous system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
-40.0 °F - closed cup
flash_point_c
-40 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
35 years of palladium-catalyzed cross-coupling with Grignard reagents: how far have we come?
Knappke CEI and von Wangelin AJ
Chemical Society Reviews, 40(10), 4948-4962 (2011)
Versatile method for introduction of bulky substituents to alkoxychlorosilanes
Masaoka S, et al.
Journal of Organometallic Chemistry, 691(1-2), 182-192 (2006)
An unprecedented iron-catalyzed cross-coupling of primary and secondary alkyl Grignard reagents with non-activated aryl chlorides
Perry MC, et al.
Tetrahedron Letters, 53(33), 4436-4439 (2012)
Jee Myung Yang et al.
BMC ophthalmology, 17(1), 101-101 (2017-06-28)
Physical cooling of the eye surface relieves ocular discomfort, but translating this event to drug treatment of dry eye discomfort not been studied. Here, we synthesized a water-soluble TRPM8 receptor agonist called cryosim-3 (C3, 1-diisopropylphosphorylnonane) which selectively activates TRPM8 (linked
商品
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
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