Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Kilo-Lab® of , Sure/Seal™ of
concentration
2.0 M in THF
density
~1.02 g/mL at 20 °C, 1.042 g/mL at 25 °C
SMILES string
Cl[Mg]c1ccccc1
InChI
1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
InChI key
GQONLASZRVFGHI-UHFFFAOYSA-M
Application
苯基氯化镁 (PhMgCl) 溶液是一种常用的格氏试剂，用于合成 (-) - 苯羟基丙氨酸和 stephacidin B。它用于多种交叉偶联反应。 它也可以与氯化铝 (AlCl3) 一起在可充电镁电池中用作电解质溶液。
Packaging
查看可回收的容器产品。
Other Notes
25°C 以下储存可能会形成结晶镁盐。将容器移动至温暖位置，偶尔轻轻涡旋应使固体重新溶解
Legal Information
Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Asymmetric synthesis of pyrrolidinoindolines. Application for the practical total synthesis of (−)-phenserine
Huang A, et al.
Journal of the American Chemical Society, 126(43), 14043-14053 (2004)
Enantioselective synthesis of stephacidin B.
Herzon S, et al.
Journal of the American Chemical Society, 127(15), 5342-5344 (2005)
Nickel-Catalyzed Cross-Coupling of Aryl Chlorides with Aryl Grignard Reagents.
B ohm VPW, et al.
Angewandte Chemie (International Edition in English), 39(9), 1602-1604 (2000)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 224448-800ML | 04061838779045 |
| 224448-8L | 04061838125712 |
| 224448-100ML | 04061838779038 |
| 224448-18L-KL | 04061838135032 |
| 224448-PZ | 04061823820066 |