224448
苯基氯化镁 溶液
2.0 M in THF
别名:
Chlorophenylmagnesium
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关于此项目
线性分子式:
C6H5MgCl
化学文摘社编号:
分子量:
136.86
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587900
产品名称
苯基氯化镁 溶液, 2.0 M in THF
InChI
1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
SMILES string
Cl[Mg]c1ccccc1
InChI key
GQONLASZRVFGHI-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in THF
density
~1.02 g/mL at 20 °C
1.042 g/mL at 25 °C
Quality Level
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Application
苯基氯化镁 (PhMgCl) 溶液是一种常用的格氏试剂，用于合成 (-) - 苯羟基丙氨酸和 stephacidin B。它用于多种交叉偶联反应。 它也可以与氯化铝 (AlCl3) 一起在可充电镁电池中用作电解质溶液。
Other Notes
25°C 以下储存可能会形成结晶镁盐。将容器移动至温暖位置，偶尔轻轻涡旋应使固体重新溶解
Packaging
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signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Nickel-Catalyzed Cross-Coupling of Aryl Chlorides with Aryl Grignard Reagents.
B ohm VPW, et al.
Angewandte Chemie (International Edition in English), 39(9), 1602-1604 (2000)
Electrolyte solutions with a wide electrochemical window for rechargeable magnesium batteries.
Mizrahi O, et al.
Journal of the Electrochemical Society, 155(2), A103-A109 (2008)
Asymmetric synthesis of pyrrolidinoindolines. Application for the practical total synthesis of (−)-phenserine
Huang A, et al.
Journal of the American Chemical Society, 126(43), 14043-14053 (2004)
Enantioselective synthesis of stephacidin B.
Herzon S, et al.
Journal of the American Chemical Society, 127(15), 5342-5344 (2005)
Functional group tolerant Kumada- Corriu- Tamao coupling of nonactivated alkyl halides with aryl and heteroaryl nucleophiles: Catalysis by a nickel pincer complex permits the coupling of functionalized Grignard reagents.
Vechorkin O, et al.
Journal of the American Chemical Society, 131(28), 9756-9766 (2009)
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