224499
叔丁基氯化镁 溶液
2.0 M in diethyl ether
别名:
t-Butylmagnesium chloride, tert-Butylchloromagnesium, Chloro(1,1-dimethylethyl)magnesium
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线性分子式:
(CH3)3CMgCl
化学文摘社编号:
分子量:
116.87
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3535403
Concentration:
2.0 M in diethyl ether
Form:
liquid
InChI
1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
SMILES string
CC(C)(C)[Mg]Cl
InChI key
ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Quality Level
form
liquid
reaction suitability
reaction type: Grignard Reaction
concentration
2.0 M in diethyl ether
density
0.828 g/mL at 25 °C
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Application
tert-Butylmagnesium chloride solution can be used as a Grignard reagent:
- In the Fe-catalyzed cross-coupling reaction with chloroenynols.
- To synthesize alkyne-terminated polyhexylthiophenes.
supp_hazards
signalword
Danger
target_organs
Central nervous system
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-40.0 °F - closed cup
flash_point_c
-40 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
法规信息
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此项目有
Self-assembly of carbohydrate-block-poly (3-hexylthiophene) diblock copolymers into sub-10 nm scale lamellar structures
Sakai-Otsuka Y, et al.
Macromolecules, 50, 3365-3376 (2017)
Abdallah Hamze et al.
The Journal of organic chemistry, 72(10), 3868-3874 (2007-04-17)
Palladium-catalyzed hydrostannation of substituted Z- and E-enynols is discussed and compared. The regioselectivity of the H-Sn bond addition was found to be controlled by the geometry of the double bond (Z- or syn-directing effect) rather than the nature of its
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