225460
二壬羰基铁
98%, solid
别名:
九碳二铁, 烯羰基二铁, 烯羰基铁
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关于此项目
线性分子式:
Fe2(CO)9
化学文摘社编号:
分子量:
363.78
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
239-359-5
MDL number:
产品名称
二壬羰基铁, 98%
InChI key
JCXLZXJCZPKTBW-UHFFFAOYSA-N
InChI
1S/9CO.2Fe/c9*1-2;;
SMILES string
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]2C(=O)[Fe]1C2=O
assay
98%
form
solid
reaction suitability
core: iron
reagent type: catalyst
storage temp.
2-8°C
Quality Level
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Application
与苯硅烷类化合物反应生成三重桥联二铁络合物。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Sol. 2 - Water-react 2
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Kerber, R. C. et al.R. C.; Ribakove, E. C.
Organometallic News, 10, 2848-2848 (1991)
Gree, R.
Synthesis, 341-341 (1989)
Simons, R.S. Tessier, C.A.
Organometallics, 15, 2604-2604 (1996)
Crump, S. L.; Netka, J.; Rickborn, B.
The Journal of Organic Chemistry, 50, 2746-2746 (1985)
Robert Ponec et al.
Journal of computational chemistry, 29(9), 1387-1398 (2008-01-16)
The nature of the bonding in the above carbonyls was studied using the analysis of domain averaged Fermi holes (DAFH). The results straightforwardly confirm the conclusions of earlier theoretical studies in which the existence of direct metal-metal bond, anticipated for
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