225460
二壬羰基铁
98%, solid
别名:
九碳二铁, 烯羰基二铁, 烯羰基铁
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关于此项目
线性分子式:
Fe2(CO)9
化学文摘社编号:
分子量:
363.78
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
239-359-5
MDL number:
产品名称
二壬羰基铁, 98%
InChI key
JCXLZXJCZPKTBW-UHFFFAOYSA-N
InChI
1S/9CO.2Fe/c9*1-2;;
SMILES string
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]2C(=O)[Fe]1C2=O
assay
98%
form
solid
reaction suitability
core: iron, reagent type: catalyst
storage temp.
2-8°C
Application
与苯硅烷类化合物反应生成三重桥联二铁络合物。
signalword
Danger
hcodes
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Sol. 2 - Water-react. 2
Gree, R.
Synthesis, 341-341 (1989)
Kerber, R. C. et al.R. C.; Ribakove, E. C.
Organometallic News, 10, 2848-2848 (1991)
Simons, R.S. Tessier, C.A.
Organometallics, 15, 2604-2604 (1996)
Luca Bertini et al.
The journal of physical chemistry. A, 111(48), 12152-12162 (2007-11-09)
The singlet and triplet state potential energy surfaces (PES) of Fe2(CO)8 are explored by means of density functional theory (DFT) techniques. The two PES have different global mimima: the dibriged C(2v) isomer for the singlet and the unbridged D(2d) isomer
Nu Xiao et al.
Dalton transactions (Cambridge, England : 2003), (4)(4), 603-608 (2006-01-13)
[{Micro-(phthalazine-N2:N3)}Fe2(micro-CO)(CO)6](1) reacts with organolithium reagents, RLi (R = CH3, C6H5, p-CH3C6H4, p-CH3OC6H4, p-CF3C6H4, p-C6H5C6H4), followed by treatment with Me3SiCl to give the novel diiron carbonyl complexes with a saturated N-N six-membered diazane ring ligand, [{C6H4CH(R)NNCH2}Fe2(C=O)(CO)6](2, R = CH3; 3, R
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