225460
二壬羰基铁
98%, solid
别名:
九碳二铁, 烯羰基二铁, 烯羰基铁
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关于此项目
线性分子式:
Fe2(CO)9
化学文摘社编号:
分子量:
363.78
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
产品名称
二壬羰基铁, 98%
质量水平
方案
98%
表单
solid
反应适用性
core: iron
reagent type: catalyst
储存温度
2-8°C
SMILES字符串
[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].O=C1[Fe]2C(=O)[Fe]1C2=O
InChI
1S/9CO.2Fe/c9*1-2;;
InChI key
JCXLZXJCZPKTBW-UHFFFAOYSA-N
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应用
与苯硅烷类化合物反应生成三重桥联二铁络合物。
警示用语：
Danger
危险分类
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Sol. 2 - Water-react 2
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Gree, R.
Synthesis, 341-341 (1989)
Kerber, R. C. et al.R. C.; Ribakove, E. C.
Organometallic News, 10, 2848-2848 (1991)
Simons, R.S. Tessier, C.A.
Organometallics, 15, 2604-2604 (1996)
Luca Bertini et al.
The journal of physical chemistry. A, 111(48), 12152-12162 (2007-11-09)
The singlet and triplet state potential energy surfaces (PES) of Fe2(CO)8 are explored by means of density functional theory (DFT) techniques. The two PES have different global mimima: the dibriged C(2v) isomer for the singlet and the unbridged D(2d) isomer
Robert Ponec et al.
Journal of computational chemistry, 29(9), 1387-1398 (2008-01-16)
The nature of the bonding in the above carbonyls was studied using the analysis of domain averaged Fermi holes (DAFH). The results straightforwardly confirm the conclusions of earlier theoretical studies in which the existence of direct metal-metal bond, anticipated for
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