225754
烯丙基溴化镁 溶液
1.0 M in diethyl ether
别名:
(Prop-2-en-1-yl)magnesium bromide, 2-Propenylmagnesium bromide, Allyl magnesium bromide, Allylbromomagnesium, Allylmagnesiumbromide, Bromo-2-propenylmagnesium
质量水平
反应适用性
reaction type: Grignard Reaction
浓度
1.0 M in diethyl ether
密度
0.851 g/mL at 25 °C
SMILES字符串
Br[Mg]CC=C
InChI
1S/C3H5.BrH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1
InChI key
FEMBXICCJNZMMC-UHFFFAOYSA-M
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一般描述
烯丙基溴化镁溶液可用作氮杂-芳香杂环（aza-aromatic heterocycle）的选择性亲核试剂。
应用
烯丙基溴化镁溶液可用于格氏反应，这是合成的关键步骤：
- 2-（9，10-二氢-9，10-丙酰基-9-基）-N-甲基乙胺（2），苯并喋呤的同系物
- tarchonanthuslactone
- （+）-preussin
- 多羟基化喹嗪类生物碱
包装
查看可回收的容器产品。
警示用语：
Danger
危险分类
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3 - Water-react 1
靶器官
Central nervous system
补充剂危害
储存分类代码
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
闪点(°F)
-40.0 °F - closed cup
闪点(°C)
-40 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
An Efficient Asymmetric Synthesis of Tarchonanthuslactone1.
Reddy M, et al.
The Journal of Organic Chemistry, 66(7), 2512-2514 (2001)
Stereoselective synthesis of the antifungal antibiotic (+)-preussin.
Veeresa G, et al.
Tetrahedron, 54(51), 15673-15678 (1998)
Synthesis of 2-(9, 10-dihydro-9, 10-propanoanthracen-9-yl)-N-methylethanamine via a [4+ 2] cycloaddition.
Karama U, et al.
Molecules (Basel), 15(6), 4201-4206 (2010)
Allylmagnesium Bromide as a selective nucleophile toward Aza-aromatic heterocycles
Henry G et al.
Journal of the American Chemical Society, 79, 1245-1249 (1957)
Synthesis of trihydroxy quinolizidine alkaloids: 1, 3-addition reaction of allylmagnesium bromide to a sugar nitrone.
Dhavale DD, et al.
Tetrahedron, 60(13), 3009-3016 (2004)
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