225908
烯丙基氯化镁 溶液
2.0 M in THF
别名:
Allyl magnesium chloride, Allylchloromagnesium, Allylmagnesium chloride, Chloro-2-propen-1-ylmagnesium
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关于此项目
线性分子式:
CH2=CHCH2MgCl
化学文摘社编号:
分子量:
100.83
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587316
Quality Level
reaction suitability
reaction type: Grignard Reaction
packaging
Kilo-Lab® of , Sure/Seal™ of
concentration
2.0 M in THF
density
0.995 g/mL at 25 °C
SMILES string
Cl[Mg]CC=C
InChI
1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1
InChI key
PLYLAFITHJUEGX-UHFFFAOYSA-M
General description
烯丙基氯化镁溶液是一种有机化合物，常用作化学反应中的作格氏试剂。它用于羰基化合物的烯丙基化，例如醛和酮。
Application
烯丙基氯化镁可作为格氏试剂用于制备：
- 抗精神病药高抗素。
- 以六氯铂酸为催化剂制备的聚硅烷–冠醚聚合物（PSEC）。
- 3,4-二氢异喹啉制备的1,7-二取代-1,2,3,4-四氢异喹啉。.
Legal Information
Kilo-Lab is a registered trademark of Merck KGaA, Darmstadt, Germany
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
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Danger
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
1.4 °F - closed cup - Solvent
flash_point_c
-17 °C - closed cup - Solvent
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1
法规信息
危险化学品
此项目有
Synthesis, In Vitro and In Silico Analysis of New Oleanolic Acid and Lupeol Derivatives against Leukemia Cell Lines: Involvement of the NF-?B Pathway
Fontana G, et al.
International Journal of Molecular Sciences, 6594-6594 (2022)
Tetrahedron Letters, 47, 9207-9207 (2006)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 225908-18L | 04061837902451 |
| 225908-100ML | 04061838779908 |
| 225908-800ML | 04061837902482 |