227234
2-均三甲苯基溴化镁 溶液
1.0 M in THF
别名:
2,4,6-三甲基苯溴化镁
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关于此项目
线性分子式:
(CH3)3C6H2MgBr
化学文摘社编号:
分子量:
223.39
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352103
MDL number:
产品名称
2-均三甲苯基溴化镁 溶液, 1.0 M in THF
InChI
1S/C9H11.BrH.Mg/c1-7-4-8(2)6-9(3)5-7;;/h4-5H,1-3H3;1H;/q;;+1/p-1
SMILES string
Cc1cc(C)c([Mg]Br)c(C)c1
InChI key
YXVSITSUDRGILL-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
1.0 M in THF
density
1.005 g/mL at 25 °C
Quality Level
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Application
2-均三甲苯基溴化镁是一种Grignard试剂，可通过动力学阻断反应性分子位点，通常用于合成稳定的芳香自由基类化合物，如苯并Z型并七苯、二茚并蒽、 teranthene和二均三甲苯茚并[2,1-a]芴。它还可用于各种芳族交叉偶联反应。
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17.0 °C - closed cup
法规信息
新产品
此项目有
Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals.
Rudebusch, Gabriel E et al.
Nature Chemistry, 8(8), 753-753 (2016)
Indeno [2, 1-a] fluorene: An Air-Stable ortho-Quinodimethane Derivative.
Shimizu A and Tobe Y
Angewandte Chemie (International Edition in English), 123(30), 7038-7042 (2011)
Highly selective biaryl cross-coupling reactions between aryl halides and aryl Grignard reagents: a new catalyst combination of N-heterocyclic carbenes and iron, cobalt, and nickel fluorides.
Hatakeyama T, et al.
Journal of the American Chemical Society, 131(33), 11949-11963 (2009)
Synthesis and characterization of teranthene: a singlet biradical polycyclic aromatic hydrocarbon having Kekule structures.
Konishi A, et al.
Journal of the American Chemical Society, 132(32), 11021-11023 (2010)
Iron-catalyzed selective biaryl coupling: Remarkable suppression of homocoupling by the fluoride anion.
Hatakeyama T and Nakamura M
Journal of the American Chemical Society, 129(32), 9844-9845 (2007)
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