227749
乙酰丙酮钼
powder
别名:
MoO2（acac）2, 乙酰丙酮钼, 二乙酰丙酮二氧化钼, 二氧化钼双（乙酰丙酮）, 二氧杂二辛基乙酸钼
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关于此项目
线性分子式:
[CH3COCH=C(O-)CH3]2MoO2
化学文摘社编号:
分子量:
326.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
241-522-0
MDL number:
产品名称
乙酰丙酮钼,
form
powder
Quality Level
reaction suitability
core: molybdenum, reagent type: catalyst
mp
184 °C (dec.) (lit.)
storage temp.
2-8°C
SMILES string
CC(=O)\C=C(\C)O[Mo](=O)(=O)O\C(C)=C/C(C)=O
InChI
1S/2C5H8O2.Mo.2O/c2*1-4(6)3-5(2)7;;;/h2*3,6H,1-2H3;;;/q;;+2;;/p-2/b2*4-3-;;;
InChI key
SKMUJBBRXZPAJY-VGKOASNMSA-L
General description
二（乙酰丙酮）氧化钼(VI) 可用作氧化转化反应的起始原料和催化剂。
Application
双（乙酰丙酮）二氧化钼（VI）可用于：
- 作为原材料，合成二氧化钼（VI）席夫（Schiff）碱配合物，此配合物作为催化剂，可用H2O2氧化醇。
- 制备氧化石墨烯负载的多相钼基催化剂，用于烯烃的环氧化。
- 作为催化剂，用于硫醇和醇的醚化反应和硫醚化反应。
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Peter Priecel et al.
Frontiers in chemistry, 8, 216-216 (2020-04-24)
This investigation deals with NiMo-alumina hydrotreating catalysts effective in the deoxygenation of rapeseed oil. The main goal was to compare catalyst structure and their deoxygenation performance and to link these parameters to reveal important structural information regarding the catalyst's intended
Covalent functionalization of graphene oxide with molybdenum-carboxylate complexes: new reusable catalysts for the epoxidation of olefins
Masteri-Farahani M and Mirshekar S
Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 538(1), 387-392 (2018)
Dinuclear and polynuclear dioxomolybdenum (VI) Schiff base complexes: synthesis, structural elucidation, spectroscopic characterization, electrochemistry and catalytic property
Ngan NK, et al.
Polyhedron, 33(1), 235-251 (2012)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 227749-50G | 04061838780935 |
| 227749-10G | 04061838780928 |