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Merck
CN

227749

乙酰丙酮钼

powder

别名:

MoO2(acac)2, 乙酰丙酮钼, 二乙酰丙酮二氧化钼, 二氧化钼双(乙酰丙酮), 二氧杂二辛基乙酸钼

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关于此项目

线性分子式:
[CH3COCH=C(O-)CH3]2MoO2
化学文摘社编号:
分子量:
326.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
241-522-0
MDL number:
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产品名称

乙酰丙酮钼,

InChI key

SKMUJBBRXZPAJY-VGKOASNMSA-L

InChI

1S/2C5H8O2.Mo.2O/c2*1-4(6)3-5(2)7;;;/h2*3,6H,1-2H3;;;/q;;+2;;/p-2/b2*4-3-;;;

SMILES string

CC(=O)\C=C(\C)O[Mo](=O)(=O)O\C(C)=C/C(C)=O

form

powder

reaction suitability

core: molybdenum
reagent type: catalyst

mp

184 °C (dec.) (lit.)

storage temp.

2-8°C

Quality Level

Application

双(乙酰丙酮)二氧化钼(VI)可用于:
  • 作为原材料,合成二氧化钼(VI)席夫(Schiff)碱配合物,此配合物作为催化剂,可用H2O2氧化醇。
  • 制备氧化石墨烯负载的多相钼基催化剂,用于烯烃的环氧化。
  • 作为催化剂,用于硫醇和醇的醚化反应和硫醚化反应。

General description

二(乙酰丙酮)氧化钼(VI) 可用作氧化转化反应的起始原料和催化剂。

pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis, structures, electrochemical studies and antioxidant activities of cis-dioxomolybdenum (VI) complexes of the new bisthiocarbohydrazones
Kaya Y, et al.
Journal of Molecular Structure, 1102, 17-126 (2015)
Dinuclear and polynuclear dioxomolybdenum (VI) Schiff base complexes: synthesis, structural elucidation, spectroscopic characterization, electrochemistry and catalytic property
Ngan NK, et al.
Polyhedron, 33(1), 235-251 (2012)
Wei Wang et al.
ACS nano, 10(11), 10106-10116 (2016-11-05)
Electrode materials based on conversion reactions with lithium ions generally show much higher energy density. One of the main challenges in the design of these electrode materials is to improve initial Coulombic efficiency and alleviate the volume changes during the
Molybdenum (VI)-catalyzed dehydrative construction of CO and CS bonds formation via etherification and thioetherification of alcohols and thiols
Singh RR, et al.
Molecular Catalysis, 492(1), 110954-110954 (2020)
Peter Priecel et al.
Frontiers in chemistry, 8, 216-216 (2020-04-24)
This investigation deals with NiMo-alumina hydrotreating catalysts effective in the deoxygenation of rapeseed oil. The main goal was to compare catalyst structure and their deoxygenation performance and to link these parameters to reveal important structural information regarding the catalyst's intended

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