234826
双(环戊二烯基)二氯化钛(IV)
97%
别名:
Cp2TiCl2, 二氯双(1,3-环戊二烯基)钛, 二氯双环戊二烯基钛, 二氯环戊二烯钛, Cp2TiCl2, 二氯二茂钛, 二氯双(环戊二烯基)钛(IV)
质量水平
方案
97%
反应适用性
core: titanium
reagent type: catalyst
mp
260-280 °C (dec.) (lit.)
密度
1.6 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key
XKLWATAZDMHTSH-UHFFFAOYSA-L
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应用
由苯甲醛和溴甲基丙烯酸酯一锅法合成 α-亚甲基-γ-丁内酯。
警示用语：
Danger
危险声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Tetrahedron Letters, 48, 3205-3205 (2007)
Samaresh Jana et al.
The Journal of organic chemistry, 70(20), 8252-8254 (2005-11-10)
[Chemical reaction: see text] A radical based Wagner-Meerwein-type rearrangement has been observed in camphoric systems. The radical was generated from the epoxide using Cp2TiCl as the radical source. The radical initiator Cp2TiCl was prepared in situ from commercially available Cp2TiCl2
[Determination of organometallic antitumor crude drug titanocene dichloride by NP-HPLC].
Yunlan Li et al.
Se pu = Chinese journal of chromatography, 25(2), 282-283 (2007-06-22)
Ramón Hernández et al.
Toxicology in vitro : an international journal published in association with BIBRA, 24(1), 178-183 (2009-09-24)
Replacement of the ancillary ligand in titanocene dichloride by amino acids provides titanocene species with high water solubility. As part of our research efforts in the area of titanium-based antitumor agents, we have investigated the cytotoxic activity of Cp(2)TiCl(2) and
A Fernandez-Mateos et al.
The Journal of organic chemistry, 72(26), 9973-9982 (2007-11-30)
The reactions of a series of epoxynitriles and epoxyketones induced by titanocene chloride have been studied. The kinetics of the decyanogenation of beta,gamma-epoxynitriles with Ti(III) corresponds to a radical reaction (k25 approximately 106 s-1), as demonstrated by competition experiments with
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