234826
双(环戊二烯基)二氯化钛(IV)
97%
别名:
Cp2TiCl2, 二氯双(1,3-环戊二烯基)钛, 二氯双环戊二烯基钛, 二氯环戊二烯钛, Cp2TiCl2, 二氯二茂钛, 二氯双(环戊二烯基)钛(IV)
质量水平
方案
97%
反应适用性
core: titanium
reagent type: catalyst
mp
260-280 °C (dec.) (lit.)
密度
1.6 g/mL at 25 °C (lit.)
SMILES字符串
Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChI key
XKLWATAZDMHTSH-UHFFFAOYSA-L
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应用
由苯甲醛和溴甲基丙烯酸酯一锅法合成 α-亚甲基-γ-丁内酯。
警示用语：
Danger
危险声明
危险分类
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Katherine M Buettner et al.
Dalton transactions (Cambridge, England : 2003), 40(37), 9580-9588 (2011-08-19)
Since the discovery of the anticancer activity of titanocene dichloride (TDC), many derivatives have been developed and evaluated. MKT4, a soluble, water-stable formulation of TDC, was used for both Phase I and Phase II human clinical trials. This formulation is
Alberto García-Peñas et al.
Journal of inorganic biochemistry, 106(1), 100-110 (2011-11-25)
Titanocene dichloride [Ti(η(5)-C(5)H(5))(2)Cl(2)] (1), has been grafted onto dehydrated hydroxyapatite (HAP), Al(2)O(3) and two mesoporous silicas MSU-2 (Michigan State University Silica type 2) and HMS (Hexagonal Mesoporous Silica), to give the novel materials HAP/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S1) (1.01 wt.% Ti), Al(2)O(3)/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S2)
Li Ming Gao et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 12(7), 959-967 (2007-06-15)
Functionalization of cyclopentadienyl (Cp) ligands and incorporation of these into a Ti(IV) center require careful design and selection of the appropriate synthetic routes to obtain the desired product in reasonably good yields. As part of our research efforts in the
Francesco Caruso et al.
Mini reviews in medicinal chemistry, 4(1), 49-60 (2004-02-03)
Most anticancer titanium compounds act against tumors in the gastrointestinal tract. Activity towards breast, lung and skin (melanoma) cancers is shown by some as well. Among their appealing properties is that they do not show common side effects of widely
Mauro Ravera et al.
Journal of inorganic biochemistry, 99(12), 2264-2269 (2005-10-08)
Titanocene dichloride exhibits anti-proliferative activity in a wide spectrum of murine and human tumors. Although it is still unclear as to which species are active in biological media, they all readily deliver Ti(IV) to transferrin, the protein that transports iron
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