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234826

双(环戊二烯基)二氯化钛(IV)

Name: 双(环戊二烯基)二氯化钛(IV)
Brand: ALDRICH

97%

别名:

Cp2TiCl2, 二氯双(1,3-环戊二烯基)钛, 二氯双环戊二烯基钛, 二氯环戊二烯钛, Cp₂TiCl₂, 二氯二茂钛, 二氯双(环戊二烯基)钛(IV)

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关于此项目

经验公式（希尔记法）:

C₁₀H₁₀Cl₂Ti

化学文摘社编号:

1271-19-8

分子量:

248.96

NACRES:

NA.22

PubChem Substance ID:

24854058

UNSPSC Code:

12161600

EC Number:

215-035-9

MDL number:

MFCD00003723

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属性

assay

97%

reaction suitability

core: titanium, reagent type: catalyst

mp

260-280 °C (dec.) (lit.)

density

1.6 g/mL at 25 °C (lit.)

SMILES string

Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

InChI

1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

InChI key

XKLWATAZDMHTSH-UHFFFAOYSA-L

说明

Application

由苯甲醛和溴甲基丙烯酸酯一锅法合成 α-亚甲基-γ-丁内酯。

pictograms

GHS05,GHS07,GHS09

signalword

Danger

hcodes

H318,H335,H410

pcodes

P261 - P271 - P273 - P280 - P304 + P340 + P312 - P305 + P351 + P338

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis, Ti(IV) intake by apotransferrin and cytotoxic properties of functionalized titanocene dichlorides.

Li Ming Gao et al.

Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 12(7), 959-967 (2007-06-15)

Functionalization of cyclopentadienyl (Cp) ligands and incorporation of these into a Ti(IV) center require careful design and selection of the appropriate synthetic routes to obtain the desired product in reasonably good yields. As part of our research efforts in the

Study of the cytotoxicity and particle action in human cancer cells of titanocene-functionalized materials with potential application against tumors.

Alberto García-Peñas et al.

Journal of inorganic biochemistry, 106(1), 100-110 (2011-11-25)

Titanocene dichloride [Ti(η(5)-C(5)H(5))(2)Cl(2)] (1), has been grafted onto dehydrated hydroxyapatite (HAP), Al(2)O(3) and two mesoporous silicas MSU-2 (Michigan State University Silica type 2) and HMS (Hexagonal Mesoporous Silica), to give the novel materials HAP/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S1) (1.01 wt.% Ti), Al(2)O(3)/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S2)

Pharmaceutical formulation affects titanocene transferrin interactions.

Katherine M Buettner et al.

Dalton transactions (Cambridge, England : 2003), 40(37), 9580-9588 (2011-08-19)

Since the discovery of the anticancer activity of titanocene dichloride (TDC), many derivatives have been developed and evaluated. MKT4, a soluble, water-stable formulation of TDC, was used for both Phase I and Phase II human clinical trials. This formulation is

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全球贸易项目编号

货号	GTIN
234826-10G	04061838784704
234826-50G	04061838784711