234826
双(环戊二烯基)二氯化钛(IV)
97%
别名:
Cp2TiCl2, 二氯双(1,3-环戊二烯基)钛, 二氯双环戊二烯基钛, 二氯环戊二烯钛, Cp2TiCl2, 二氯二茂钛, 二氯双(环戊二烯基)钛(IV)
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关于此项目
经验公式（希尔记法）:
C10H10Cl2Ti
化学文摘社编号:
分子量:
248.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-035-9
MDL number:
产品名称
双(环戊二烯基)二氯化钛(IV), 97%
InChI key
XKLWATAZDMHTSH-UHFFFAOYSA-L
InChI
1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
SMILES string
Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
assay
97%
reaction suitability
core: titanium
reagent type: catalyst
mp
260-280 °C (dec.) (lit.)
density
1.6 g/mL at 25 °C (lit.)
Quality Level
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Application
由苯甲醛和溴甲基丙烯酸酯一锅法合成 α-亚甲基-γ-丁内酯。
signalword
Danger
hcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
dust mask type N95 (US), Eyeshields, Gloves
Sandra Cuffe et al.
The Prostate, 71(2), 111-124 (2010-07-29)
While locally advanced prostate cancer is initially treatable with androgen ablation, eventually cells develop a castrate-resistant phenotype. Currently, there are no effective treatments for this form of the disease with Docetaxel only providing a small survival advantage. In this study
A Fernandez-Mateos et al.
The Journal of organic chemistry, 72(26), 9973-9982 (2007-11-30)
The reactions of a series of epoxynitriles and epoxyketones induced by titanocene chloride have been studied. The kinetics of the decyanogenation of beta,gamma-epoxynitriles with Ti(III) corresponds to a radical reaction (k25 approximately 106 s-1), as demonstrated by competition experiments with
[Determination of organometallic antitumor crude drug titanocene dichloride by NP-HPLC].
Yunlan Li et al.
Se pu = Chinese journal of chromatography, 25(2), 282-283 (2007-06-22)
Tetrahedron Letters, 48, 3205-3205 (2007)
Ramón Hernández et al.
Toxicology in vitro : an international journal published in association with BIBRA, 24(1), 178-183 (2009-09-24)
Replacement of the ancillary ligand in titanocene dichloride by amino acids provides titanocene species with high water solubility. As part of our research efforts in the area of titanium-based antitumor agents, we have investigated the cytotoxic activity of Cp(2)TiCl(2) and
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