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Merck
CN

234826

双(环戊二烯基)二氯化钛(IV)

97%

别名:

Cp2TiCl2, 二氯双(1,3-环戊二烯基)钛, 二氯双环戊二烯基钛, 二氯环戊二烯钛, Cp2TiCl2, 二氯二茂钛, 二氯双(环戊二烯基)钛(IV)

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关于此项目

经验公式(希尔记法):
C10H10Cl2Ti
化学文摘社编号:
分子量:
248.96
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12161600
EC Number:
215-035-9
MDL number:
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InChI key

XKLWATAZDMHTSH-UHFFFAOYSA-L

InChI

1S/2C5H5.2ClH.Ti/c2*1-2-4-5-3-1;;;/h2*1-5H;2*1H;/q;;;;+2/p-2

SMILES string

Cl[Ti]Cl.[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2

assay

97%

reaction suitability

core: titanium, reagent type: catalyst

mp

260-280 °C (dec.) (lit.)

density

1.6 g/mL at 25 °C (lit.)

Quality Level

Application

由苯甲醛和溴甲基丙烯酸酯一锅法合成 α-亚甲基-γ-丁内酯。

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

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Katherine M Buettner et al.
Dalton transactions (Cambridge, England : 2003), 40(37), 9580-9588 (2011-08-19)
Since the discovery of the anticancer activity of titanocene dichloride (TDC), many derivatives have been developed and evaluated. MKT4, a soluble, water-stable formulation of TDC, was used for both Phase I and Phase II human clinical trials. This formulation is
Alberto García-Peñas et al.
Journal of inorganic biochemistry, 106(1), 100-110 (2011-11-25)
Titanocene dichloride [Ti(η(5)-C(5)H(5))(2)Cl(2)] (1), has been grafted onto dehydrated hydroxyapatite (HAP), Al(2)O(3) and two mesoporous silicas MSU-2 (Michigan State University Silica type 2) and HMS (Hexagonal Mesoporous Silica), to give the novel materials HAP/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S1) (1.01 wt.% Ti), Al(2)O(3)/[Ti(η(5)-C(5)H(5))(2)Cl(2)] (S2)
Francesco Caruso et al.
Mini reviews in medicinal chemistry, 4(1), 49-60 (2004-02-03)
Most anticancer titanium compounds act against tumors in the gastrointestinal tract. Activity towards breast, lung and skin (melanoma) cancers is shown by some as well. Among their appealing properties is that they do not show common side effects of widely
Ping Chen et al.
European journal of pharmaceutics and biopharmaceutics : official journal of Arbeitsgemeinschaft fur Pharmazeutische Verfahrenstechnik e.V, 76(3), 413-420 (2010-09-22)
In order to improve both safety and efficacy of cancer chemotherapy of titanocene dichloride and overcome the shortcomings such as instability and short half-life in the human body, we report a controlled release system of titanocene dichloride by electrospun fiber
Seiji Takahashi et al.
The journal of physical chemistry. A, 116(2), 865-869 (2011-12-22)
Characterization of the compound Ti(C(5)H(5))(2)Cl(2) was studied using Li(+) ion attachment mass spectrometry (IAMS) as an analytical methodology. Since this target compound is used as an anticancer drug in the treatment of leukemia, accurate and rapid monitoring methods for the

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