235563
N,N′-二叔丁基碳二亚胺
99%
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关于此项目
线性分子式:
(CH3)3CN=C=NC(CH3)3
化学文摘社编号:
分子量:
154.25
UNSPSC Code:
12352001
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-719-6
Beilstein/REAXYS Number:
1758049
MDL number:
产品名称
N,N′-二叔丁基碳二亚胺, 99%
InChI key
IDVWLLCLTVBSCS-UHFFFAOYSA-N
InChI
1S/C9H18N2/c1-8(2,3)10-7-11-9(4,5)6/h1-6H3
SMILES string
CC(C)(C)N=C=NC(C)(C)C
assay
99%
reaction suitability
reaction type: Coupling Reactions
refractive index
n20/D 1.428 (lit.)
bp
48-50 °C/12 mmHg (lit.)
density
0.8 g/mL at 25 °C (lit.)
application(s)
peptide synthesis
functional group
amine
Quality Level
Gene Information
human ... EPHX2(2053)
mouse ... Ephx2(13850)
Application
N,N′-Di-tert-butylcarbodiimide can be used:
- As a reagent for the guanylation of aryl amines catalyzed by lanthanum amides.
- To prepare dichloroimidazolidine-4,5-dione by reacting with oxalyl chloride, which is a key intermediate for the synthesis of N,N′-diamidocarbenes.
- To prepare the iridium complex of benzamidine named Ir(FMeppy)2(N,N′-di-tert-butyl-4-methyl-benzamidine).
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
95.0 °F - closed cup
flash_point_c
35 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Synthesis, characterization and photophysical properties of iridium complexes with amidinate ligands
Sahin C, et al.
Journal of Organometallic Chemistry, 772, 68-78 (2014)
Qinghai Li et al.
The Journal of organic chemistry, 72(18), 6763-6767 (2007-08-07)
It is demonstrated that the cyclopentadienyl-free simple lanthanide amides [(Me(3)Si)(2)N](3)Ln(mu-Cl)Li(THF)(3)(Ln = La, Sm, Eu, Y, Yb) and Ln[N(SiMe(3))(2)]3 (Ln = Y, Yb) are highly efficient catalysts for the guanylation of both aromatic and secondary amines with a high activity under
Jonathan P Moerdyk et al.
Chemical communications (Cambridge, England), 50(35), 4551-4553 (2014-03-29)
The synthesis of the first stable, five-membered N,N'-diamidocarbenes (DACs), including a differentially N-substituted derivative, was achieved via the reduction of a geminal dichloride precursor using potassium. Key differences between the reactivity of the five-membered DACs and their six-membered congeners were
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