23955
1-(氯-1-吡咯烷基亚甲基)吡咯烷鎓六氟磷酸盐
≥97.5% (CHN)
别名:
N,N,N′,N′-双(四亚甲基)氯代甲酰胺六氟磷酸盐, PyClU, 氯代-N,N,N′,N′-双(四亚甲基)甲酰胺六氟磷酸盐
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关于此项目
线性分子式:
C9H16N2Cl · PF6
化学文摘社编号:
分子量:
332.65
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
7898575
InChI
1S/C9H16ClN2.F6P/c10-9(11-5-1-2-6-11)12-7-3-4-8-12;1-7(2,3,4,5)6/h1-8H2;/q+1;-1
SMILES string
F[P-](F)(F)(F)(F)F.Cl\C(N1CCCC1)=[N+]2/CCCC2
InChI key
NHEGCUSBUWGOQM-UHFFFAOYSA-N
assay
≥97.5% (CHN)
form
solid
reaction suitability
reaction type: Coupling Reactions
mp
153-156 °C
application(s)
peptide synthesis
functional group
chloro
storage temp.
2-8°C
Quality Level
Application
Reactant for:
Enantioselective desymmetrization of meso-asiridines
Peptide coupling
Reagent for:
Heterocyclization of chloroformamidinium salts
Oxidative insertion for palladium and nickel catalyst synthesis
Enantioselective desymmetrization of meso-asiridines
Peptide coupling
Reagent for:
Heterocyclization of chloroformamidinium salts
Oxidative insertion for palladium and nickel catalyst synthesis
Other Notes
结晶的、不吸湿的新型肽偶联试剂，尤其适用于 N-甲基氨基酸
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
J. Coste et al.
Tetrahedron Letters, 32, 1967-1967 (1991)
商品
Fluoroamidinium salts advance acid halogenation with greater stability and no oxazolones conversion compared to chlorides.
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