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Merck
CN

239658

双酚 A

≥99%

别名:

2,2-双(4-羟基苯基)丙烷, 4,4′-异亚丙基联苯酚

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关于此项目

线性分子式:
(CH3)2C(C6H4OH)2
化学文摘社编号:
80-05-7
分子量:
228.29
UNSPSC Code:
12352200
NACRES:
NA.21
PubChem Substance ID:
24854386
EC Number:
201-245-8
Beilstein/REAXYS Number:
1107700
MDL number:
MFCD00002366

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InChI key

IISBACLAFKSPIT-UHFFFAOYSA-N

InChI

1S/C15H16O2/c1-15(2,11-3-7-13(16)8-4-11)12-5-9-14(17)10-6-12/h3-10,16-17H,1-2H3

SMILES string

CC(C)(c1ccc(O)cc1)c2ccc(O)cc2

assay

≥99%

form

solid

bp

220 °C/4 mmHg (lit.)

mp

158-159 °C (lit.)

Quality Level

100

Gene Information

mouse ... Esr1(13982)
rat ... Ar(24208)

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相关类别

General description

双酚 A（BPA）是一种二苯甲烷衍生物，常用于生产聚碳酸酯塑料、环氧树脂和各种其他塑料消费品。它还显示出很强的内分泌干扰能力。
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Application

分析标准品还可用于以下用途:
  • 基于结晶共价有机骨架（COF）的改性玻碳电极（GCE）传感器对矿泉水瓶、聚碳酸酯瓶和婴儿奶瓶三种塑料制品样品中的双酚 A 和双酚 S 进行定量分析
  • 在超声辅助萃取后通过液相色谱-质谱法（LC-MS）测定 112 份热敏纸收据样品中双酚 A、S 和 F 的含量
  • 开发和验证气相色谱-串联质谱（GC-MS/MS）法，以便在固相萃取（SPE）后测定 30 份母乳样品双酚 A 和 18 种 BPA 相关化合物的含量
  • 构建基于多壁碳纳米管（MWCNT）修饰玻碳电极（GCE）的电化学传感器，以便通过循环伏安法（CV）测定河水和热敏纸样品中的双酚 A & S
  • 使用基于小型 QuEChERS 萃取和气相色谱-质谱法（GC-MS）的新颖方法测定尿液中的双酚 A
  • 采用高效液相色谱法（HPLC）调查玻璃移液器和巴斯德吸管中的产妇生物液双酚 A 含量。

signalword

Danger

target_organs

Respiratory system

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

440.6 °F - closed cup

flash_point_c

227 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - ED ENV 1 - ED HH 1 - Eye Dam. 1 - Repr. 1B - Skin Sens. 1 - STOT SE 3

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCQ9051
MKCM7053
MKCG8489
MKCD7508
MKCC7654

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Sanjay Basak et al.
Reproductive toxicology (Elmsford, N.Y.), 82, 72-79 (2018-10-24)
Humans are exposed to Bisphenol A (BPA) from the consumer products and plastic substances. However, impacts of low levels of BPA exposure on placental developmental processes such as first trimester trophoblast cell growth, angiogenesis and epigenetic modifications are not well
Maternal bisphenol-A levels at delivery: a looming problem?
Padmanabhan V, et al.
Journal of Perinatology : Official Journal of the California Perinatal Association, 28, 258-258 (2008)
Tinne Geens et al.
Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association, 50(10), 3725-3740 (2012-08-15)
Due to the large number of applications of bisphenol-A (BPA), the human exposure routes are multiple. We aimed to review shortly the food and non-food sources of BPA, and to evaluate their contribution to the human exposure. Food sources discussed
Marie Tohmé et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 28(7), 3124-3133 (2014-04-20)
Bisphenol A (BPA) is an endocrine disruptor that displays estrogenic activity. Several reports suggest that BPA may have estrogen receptor-independent effects. In zebrafish, 50 μM BPA exposure induces otic vesicle abnormalities, including otolith aggregation. The purpose of this study was
Albert A Koelmans et al.
Environmental pollution (Barking, Essex : 1987), 187, 49-54 (2014-01-21)
It is often assumed that ingestion of microplastics by aquatic species leads to increased exposure to plastic additives. However, experimental data or model based evidence is lacking. Here we assess the potential of leaching of nonylphenol (NP) and bisphenol A
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实验方案

Determination of Bisphenol A in Drinking Water

A comprehensive sample preparation and analytical procedure was developed by Supelco for determining BPA in drinking water.

饮用水中双酚 A 的测定

Supelco开发了一种可测定饮用水中的BPA的全面样品制备和分析程序。

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