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Merck
CN

244112

Sigma-Aldrich

钛酸四丁酯

reagent grade, 97%

别名:

TNBT, TYZOR® TBT 有机钛酸盐, 原钛酸丁酯, 四正丁醇钛, 正钛酸丁酯

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关于此项目

线性分子式:
Ti(OCH2CH2CH2CH3)4
CAS Number:
分子量:
340.32
Beilstein:
4148236
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23
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等级

reagent grade

质量水平

方案

97%

表单

liquid (or viscous liquid)
liquid

反应适用性

core: titanium
reagent type: catalyst

折射率

n20/D 1.491 (lit.)

沸点

206 °C/10 mmHg (lit.)

密度

1.00 g/mL at 20 °C (lit.)

SMILES字符串

CCCCO[Ti](OCCCC)(OCCCC)OCCCC

InChI

1S/4C4H9O.Ti/c4*1-2-3-4-5;/h4*2-4H2,1H3;/q4*-1;+4

InChI key

YHWCPXVTRSHPNY-UHFFFAOYSA-N

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一般描述

钛酸四丁酯是有机金属化合物,可溶于非极性和中等极性的有机溶剂。常作为前体制备二氧化钛纳米颗粒和薄膜,用于电子、涂层和光催化等领域。钛酸四丁酯可合成二氧化钛,用于太阳能电池(如钙钛矿太阳能电池)和电子发射纳米器件。二氧化钛还用作制造锂离子电池、超级电容器、有机发光器件(OLED)和电致发光器件。

应用

用于制备锐钛矿型纳米二氧化钛和铁电性 Bi4Ti3O12 薄膜。用于室温下制备纳米晶体 TiO2 粉末。
钛酸四丁酯可用于:

  • 作为催化剂,用于甲基丙烯酸甲酯的酯交换,以及香草醛基二聚物合成可再生聚酯。
  • 作为前体合成Bi4Ti3O12铁电薄膜。
  • 作为催化剂用于通过缩聚反应合成脂肪−芳香共聚酯类。
  • 作为前体经由溶胶-凝胶法合成二氧化钛(TiO2)纳米复合物粉末,用于污染物的光催化降解。
  • 作为前体经由多醇介导的合成方法合成TiO纳米颗粒(锐钛矿型和金红石型)。
  • 作为前体经由水热法合成二氧化钛纳米棒,用作钙钛矿太阳能电池(PSC)的电子传输层(ETL)。
  • 作为前体合成TiO2涂层,提高Rb0.1Cs0.9PbBrI2钙钛矿量子点(PQD)的稳定性和发光性,用于显示装置的白色发光二极管(WLED)和色彩转换。

特点和优势

  • 钛酸四丁酯具有低粘度,可更好地渗透和均匀地涂覆在各种基体上。
  • 因良好的热稳定性在高温工艺中表现优异,可在升温时保持化学完整和性能。
  • 溶于无水乙醇、醚、苯和氯仿。

法律信息

TYZOR is a registered trademark of E. I. du Pont de Nemours and Company

警示用语:

Danger

危险分类

Eye Dam. 1 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Central nervous system, Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 1

闪点(°F)

107.6 °F - Pensky-Martens closed cup

闪点(°C)

42 °C - Pensky-Martens closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Anton S Poluboyarinov et al.
Materials (Basel, Switzerland), 12(9) (2019-05-10)
Due to their unique physical and chemical properties, monodisperse titanium oxide microspheres can be used in dye-sensitized solar cells, as cosmetic pigments, and for other applications. However, the synthesis of microspheres with narrow size distribution, desired phase composition, and porosity
S Anantharaj et al.
Biomacromolecules, 13(8), 2446-2455 (2012-06-21)
A new dual ester-urethane melt condensation methodology for biological monomers-amino acids was developed to synthesize new classes of thermoplastic polymers under eco-friendly and solvent-free polymerization approach. Naturally abundant L-amino acids were converted into dual functional ester-urethane monomers by tailor-made synthetic
Huaqiang Zhuang et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 16(7), 1352-1355 (2015-02-26)
Ternary core-shell heterostructured rutile@anatase@Crx Oy nanorod arrays were elaborately designed as photoanodes for efficient photoelectrochemical water splitting under visible-light illumination. The four-fold enhanced and stabilized visible-light photocurrent highlights the unique role of the interim anatase layer in accelerating the interfacial
Jun-Bing Fan et al.
Chemical communications (Cambridge, England), 46(31), 5805-5807 (2010-07-01)
A low cost and environmentally benign process for tetrabutyl titanate-controlled ring-opening polymerization of epsilon-caprolactone at ambient temperature of 10-40 degrees C is introduced affording poly(epsilon-caprolactone) with pre-designed molecular weights and narrow molecular weight distribution.
Jun Lu et al.
Nature communications, 5, 5693-5693 (2014-12-17)
The capacity fade of lithium manganate-based cells is associated with the dissolution of Mn from cathode/electrolyte interface due to the disproportionation reaction of Mn(III), and the subsequent deposition of Mn(II) on the anode. Suppressing the dissolution of Mn from the

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