254037
氯化三苯基磷金(I)
≥99.9% trace metals basis, solid
别名:
(Ph3P)AuCl, 三苯基膦氯化金(I)
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关于此项目
线性分子式:
[(C6H5)3P]AuCl
化学文摘社编号:
分子量:
494.71
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22
产品名称
氯化三苯基磷金(I), ≥99.9% trace metals basis
质量水平
方案
≥99.9% trace metals basis
表单
solid
反应适用性
core: gold
reagent type: catalyst
SMILES字符串
Cl[Au].c1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI
1S/C18H15P.Au.ClH/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;/h1-15H;;1H/q;+1;/p-1
InChI key
IFPWCRBNZXUWGC-UHFFFAOYSA-M
应用
在室温下通过5-exo-digonal 途径将O-炔丙基氨基甲酸酯环化为亚烷基新恶唑烷酮（alkylideneoxazolidinones ）的催化剂。在室温下也催化含环烯烃的烯炔的环化异构化，生成高度稠合的多环二烯。
该试剂可与助催化卤化物提取剂一起使用以激活 π-系统通过杂原子和碳亲核试剂进行加成。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Leseurre, L. et al.
Organic Letters, 9 (2007)
Elena Barreiro et al.
Journal of inorganic biochemistry, 102(2), 184-192 (2007-09-18)
The reaction of triphenylphosphinegold(I) chloride in ethanol in a 1:1 molar ratio with the 3-(aryl)-2-sulfanylpropenoic acids H(2)xspa [x: p=3-phenyl-, Clp=3-(2-chlorophenyl)-, -o-mp=3-(2-methoxyphenyl)-, -p-mp=3-(4-methoxyphenyl)-, -o-hp=3-(2-hydroxyphenyl)-, -p-hp=3-(4-hydroxyphenyl)-, diBr-o-hp=3-(3,5-dibromo-2-hydroxyphenyl)-, f=3-(2-furyl)-, t=3-(2-thienyl)-, -o-py=3-(2-pyridyl)-; spa=2-sulfanylpropenoato] gave compounds of the type [Au(PPh(3))(Hxspa)], which were isolated and characterized
Ming Zhang et al.
Molecules (Basel, Switzerland), 17(3), 2812-2822 (2012-03-08)
An efficient method for the synthesis of β-enaminones and β-enaminoesters using a combination of [(PPh(3))AuCl]/AgOTf as catalyst has been developed. The reaction between 1,3-dicarbonyl compounds and primary amines was carried out under solvent-free conditions with low catalyst loading in good
Synlett, 3309-3309 (2006)
Gregory L Hamilton et al.
Science (New York, N.Y.), 317(5837), 496-499 (2007-07-28)
Traditionally, transition metal-catalyzed enantioselective transformations rely on chiral ligands tightly bound to the metal to induce asymmetric product distributions. Here we report high enantioselectivities conferred by a chiral counterion in a metal-catalyzed reaction. Two different transformations catalyzed by cationic gold(I)
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