255025
己基溴化镁 溶液
2.0 M in diethyl ether
别名:
1-Hexylmagnesium bromide, Bromohexylmagnesium, n-hexylmagnesium bromide
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关于此项目
线性分子式:
CH3(CH2)5MgBr
化学文摘社编号:
分子量:
189.38
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3535624
Concentration:
2.0 M in diethyl ether
Quality Segment
reaction suitability
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
2.0 M in diethyl ether
density
0.965 g/mL at 25 °C
SMILES string
CCCCCC[Mg]Br
InChI
1S/C6H13.BrH.Mg/c1-3-5-6-4-2;;/h1,3-6H2,2H3;1H;/q;;+1/p-1
InChI key
SFXUWNMDTWQSHE-UHFFFAOYSA-M
General description
Hexylmagnesium bromide, also known as n-hexylmagnesium bromide, is a useful organomagnesium compound that is commonly used in organic synthesis. It is typically prepared by reacting magnesium turnings with 1-bromohexane in diethyl ether solvent.
Application
Hexylmagnesium bromide solution can be used as a reagent in addition reactions. It can add to various electrophiles, such as carbonyl compounds, to form alcohols or carboxylic acids. These types of reactions are commonly used for the synthesis of pharmaceuticals, natural products, and other organic compounds. It is also used to reduce certain functional groups, such as ketones, esters, and nitriles, to form alcohols or amines.
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
target_organs
Central nervous system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-40.0 °F - closed cup
flash_point_c
-40 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1