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线性分子式:
CF3(CF2)5I
化学文摘社编号:
分子量:
445.95
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
206-586-6
Beilstein/REAXYS Number:
1802118
MDL number:
Assay:
99%
Form:
liquid
产品名称
全氟己基碘, 99%
InChI key
BULLJMKUVKYZDJ-UHFFFAOYSA-N
InChI
1S/C6F13I/c7-1(8,3(11,12)5(15,16)17)2(9,10)4(13,14)6(18,19)20
SMILES string
FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)I
assay
99%
form
liquid
refractive index
n20/D 1.329 (lit.)
bp
117 °C (lit.)
density
2.063 g/mL at 25 °C (lit.)
functional group
fluoro
iodo
Quality Level
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General description
全氟己基碘化物可与多种氢键受体形成1:1配合物。可通过自由基反应将其接枝到异丁烯/丙烯共聚物上,生成带有氟化侧链的聚(α-烯烃)。以偶氮二异丁腈(AIBN)为引发剂,全氟己基碘化物在醋酸乙烯酯中的自由基加成反应已有研究。
存储类别
10 - Combustible liquids
wgk
WGK 1
flash_point_f
239.0 °F - closed cup
flash_point_c
115 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Effect of reaction conditions on the radical addition of perfluorohexyl iodide to vinyl acetate.
Napoli M, et al.
Journal of Fluorine Chemistry, 57(1), 219-227 (1992)
Rafel Cabot et al.
Chemical communications (Cambridge, England), (15)(15), 2005-2007 (2009-04-01)
Quantitative studies of the 1 : 1 complexes formed between perfluorohexyl iodide and a variety of hydrogen-bond acceptors have been used to probe the relationship between halogen bonding, hydrogen bonding, desolvation and the electrostatics of non-covalent interactions.
Zirconocene-MAO-catalyzed homo-and copolymerizations of linear asymmetrically substituted dienes with propene: A novel strategy to functional (co) poly (a-olefin) s.
Hackmann M, et al.
Macromolecular Chemistry and Physics, 199(8), 1511-1517 (1998)
Alexander A Marchione et al.
Journal of magnetic resonance (San Diego, Calif. : 1997), 286, 143-147 (2017-12-16)
A train of BURBOP universal rotation pulses has been used to generate a spin lock sufficient to observe TOCSY correlations over a 46 kHz
Qian S Liu et al.
Environmental science & technology, 51(17), 10173-10183 (2017-07-27)
Per- and polyfluoroalkyl substances (PFASs) are a global concern because of their ubiquitous occurrence and high persistence in human blood, and increasing amounts of unidentified fluorinated compounds are now becoming new exposure issues. This study aims to investigate the structure-related
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