产品名称
2,6-二氟苯甲醛, 98%
InChI
1S/C7H4F2O/c8-6-2-1-3-7(9)5(6)4-10/h1-4H
SMILES string
Fc1cccc(F)c1C=O
InChI key
SOWRUJSGHKNOKN-UHFFFAOYSA-N
assay
98%
form
liquid
refractive index
n20/D 1.502 (lit.)
bp
82-84 °C/15 mmHg (lit.)
mp
15-17 °C (lit.)
density
1.317 g/mL at 25 °C (lit.)
functional group
aldehyde
fluoro
storage temp.
2-8°C
Quality Level
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Application
2,6-Difluorobenzaldehyde can be used as a reactant to synthesize:
- 5-Cyano-6-(2,6-difluorophenyl)-5,6-dihydro-2-thiouracil via one-pot cyclocondensation reaction with ethyl cyanoacetate and thiourea.
- 1-(2,6-Difluorobenzyl)-2-(2,6-difluorophenyl)-benzimidazole by reacting with 1,2-phenylenediamine in the presence of a catalytic amount of p-toluenesulfonic acid.
- (3E)-4-(2,6-Difluorophenyl)-3-buten-2-one by Wittig olefination reaction with acetylmethylidenetriphenyl phosphorane.
- Methyl 4-fluorobenzo[b]thiophene-2-carboxylate by treating with methyl thioglycolate in the presence of K2CO3.
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 2
flash_point_f
180.5 °F - closed cup
flash_point_c
82.5 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Some observations on the base-catalyzed cyclocondensation of 2, 6-dihalobenzaldehydes, ethyl cyanoacetate, and thiourea
Al-Omar Mohamed A, et al.
Synthetic Communications, 40(10), 1530-1538 (2010)
Solventless Wittig olefination with fluorinated benzaldehydes
Thiemann, Thies
J. Chem. Res. (M), 2007(6), 336-341 (2007)
Microwave-assisted synthesis of benzimidazole and thiazolidinone derivatives as HIV-1 RT inhibitors
Rao Angela, et al.
ARKIVOC (Gainesville, FL, United States), 5, 147-155 (2004)
4-Substituted (benzo [b] thiophene-2-carbonyl) guanidines as novel Na+/H+ exchanger isoform-1 (NHE-1) inhibitors
Lee Sunkyung, et al.
Bioorganic & Medicinal Chemistry Letters, 15(12), 2998-3001 (2005)
A systematic method of promoting an aryl fluoride to coordinate to ruthenium (11).
Inorgorganica Chimica Acta, 228(2), 127-131 (1995)
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