266086
铜
99.5% trace metals basis, powder, <425 μm
别名:
Cu
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关于此项目
经验公式（希尔记法）:
Cu
化学文摘社编号:
分子量:
63.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12141711
EC Number:
231-159-6
MDL number:
产品名称
铜, powder, <425 μm, 99.5% trace metals basis
InChI key
RYGMFSIKBFXOCR-UHFFFAOYSA-N
InChI
1S/Cu
SMILES string
[Cu]
assay
99.5% trace metals basis
form
powder
reaction suitability
core: copper, reagent type: catalyst
resistivity
1.673 μΩ-cm, 20°C
particle size
<425 μm
bp
2567 °C (lit.)
mp
1083.4 °C (lit.)
density
8.94 g/mL at 25 °C (lit.)
Quality Level
Application
用作环化和偶联反应的催化剂；例如，Ullmann偶联反应、环丙烷的制备、重氮酮或重氮酯的分解、C-O键的插入、末端炔烃和叠氮化物的[3+2]环加成反应和氢化反应。
存储类别
4.1B - Flammable solid hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Hiroshi Sato et al.
Science (New York, N.Y.), 343(6167), 167-170 (2013-12-18)
Carbon monoxide (CO) produced in many large-scale industrial oxidation processes is difficult to separate from nitrogen (N2), and afterward, CO is further oxidized to carbon dioxide. Here, we report a soft nanoporous crystalline material that selectively adsorbs CO with adaptable
Seonah Kim et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(1), 149-154 (2013-12-18)
Lytic polysaccharide monooxygenases (LPMOs) exhibit a mononuclear copper-containing active site and use dioxygen and a reducing agent to oxidatively cleave glycosidic linkages in polysaccharides. LPMOs represent a unique paradigm in carbohydrate turnover and exhibit synergy with hydrolytic enzymes in biomass
Stephen G Kaler et al.
The New England journal of medicine, 358(6), 605-614 (2008-02-08)
Menkes disease is a fatal neurodegenerative disorder of infancy caused by diverse mutations in a copper-transport gene, ATP7A. Early treatment with copper injections may prevent death and illness, but presymptomatic detection is hindered by the inadequate sensitivity and specificity of
Daniel L Priebbenow et al.
Organic letters, 15(24), 6155-6157 (2013-11-28)
A method has been developed for the preparation of N-alkynylated sulfoximines involving the copper-catalyzed decarboxylative coupling of sulfoximines with aryl propiolic acids. A range of substituents on both the sulfoximidoyl moiety and the aryl group of the propiolic acid were
Huawen Huang et al.
Organic letters, 15(24), 6254-6257 (2013-11-23)
A rapid and environmentally friendly conversion of pyridine to imidazo[1,2-a]pyridines has been developed via copper-catalyzed aerobic dehydrogenative cyclization with ketone oxime esters.
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