266086
铜
99.5% trace metals basis, powder, <425 μm
别名:
Cu
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关于此项目
经验公式（希尔记法）:
Cu
化学文摘社编号:
分子量:
63.55
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12141711
EC Number:
231-159-6
MDL number:
产品名称
铜, powder, <425 μm, 99.5% trace metals basis
InChI key
RYGMFSIKBFXOCR-UHFFFAOYSA-N
InChI
1S/Cu
SMILES string
[Cu]
assay
99.5% trace metals basis
form
powder
reaction suitability
core: copper, reagent type: catalyst
resistivity
1.673 μΩ-cm, 20°C
particle size
<425 μm
bp
2567 °C (lit.)
mp
1083.4 °C (lit.)
density
8.94 g/mL at 25 °C (lit.)
Quality Level
Application
用作环化和偶联反应的催化剂；例如，Ullmann偶联反应、环丙烷的制备、重氮酮或重氮酯的分解、C-O键的插入、末端炔烃和叠氮化物的[3+2]环加成反应和氢化反应。
存储类别
4.1B - Flammable solid hazardous materials
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
signalword
Warning
hcodes
pcodes
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1
Daniel L Priebbenow et al.
Organic letters, 15(24), 6155-6157 (2013-11-28)
A method has been developed for the preparation of N-alkynylated sulfoximines involving the copper-catalyzed decarboxylative coupling of sulfoximines with aryl propiolic acids. A range of substituents on both the sulfoximidoyl moiety and the aryl group of the propiolic acid were
Hiroshi Sato et al.
Science (New York, N.Y.), 343(6167), 167-170 (2013-12-18)
Carbon monoxide (CO) produced in many large-scale industrial oxidation processes is difficult to separate from nitrogen (N2), and afterward, CO is further oxidized to carbon dioxide. Here, we report a soft nanoporous crystalline material that selectively adsorbs CO with adaptable
Magnus Andersson et al.
Nature structural & molecular biology, 21(1), 43-48 (2013-12-10)
Heavy metals in cells are typically regulated by PIB-type ATPases. The first structure of the class, a Cu(+)-ATPase from Legionella pneumophila (LpCopA), outlined a copper transport pathway across the membrane, which was inferred to be occluded. Here we show by
Yan Meng et al.
Biochimica et biophysica acta, 1690(3), 208-219 (2004-10-30)
Hepatic abnormalities in Long-Evans Cinnamon (LEC) rats, an animal model of Wilson disease (WD), were restored by the expression of the human ATP7B cDNA under the control of CAG promoter. Expression of ATP7B transcript and protein in the liver of
Seonah Kim et al.
Proceedings of the National Academy of Sciences of the United States of America, 111(1), 149-154 (2013-12-18)
Lytic polysaccharide monooxygenases (LPMOs) exhibit a mononuclear copper-containing active site and use dioxygen and a reducing agent to oxidatively cleave glycosidic linkages in polysaccharides. LPMOs represent a unique paradigm in carbohydrate turnover and exhibit synergy with hydrolytic enzymes in biomass
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