275891
(1,5-环辛二烯)二氯化钯(II)
99%
别名:
PdCl 2 (cod)
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关于此项目
经验公式（希尔记法）:
C8H12Cl2Pd
化学文摘社编号:
分子量:
285.51
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352202
EC Number:
235-161-8
MDL number:
InChI key
RRHPTXZOMDSKRS-PHFPKPIQSA-L
InChI
1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
SMILES string
Cl[Pd]Cl.C1CC=CCCC=C1
assay
99%
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
mp
210 °C (dec.) (lit.)
Quality Level
Application
二氯（1,5-环辛二烯）钯 (II) 是常用的保护醇类缩醛的催化剂。以丙二酸二乙酯为原料，经烯烃羰基化合成双环辛烷。也可用于催化未活化的乙烯磷酸酯与缺电子烯烃的 Heck 偶联反应；从噻吩合成苯并[b]噻吩，并制备用于 Mizoroki-Heck 和 Suzuki-Miyaura 交叉偶联反应的活性催化剂。
用于 C-C 键和 C-N 形成的催化剂，用于炔烃与烯烃的 Heck 偶联，芳基溴化物的 Suzuki 交叉偶联，肟与烯丙基乙酸酯的烯丙基取代，和碘苯的甲氧基羰基化。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Dichloro(1,5?cyclooctadiene)palladium(II).
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2009)
Cyclic Diolefin Complexes of Platinum and Palladium.
Inorg. Synth. (2007)
An inexpensive and highly stable ligand 1, 4-bis (2-hydroxy-3, 5-di-tert-butylbenzyl) piperazine for Mizoroki?Heck and room temperature Suzuki?Miyaura cross-coupling reactions.
Mohanty S, et al.
Tetrahedron, 64(1), 240-247 (2008)
Eda Rami Reddy et al.
Dalton transactions (Cambridge, England : 2003), 44(40), 17600-17616 (2015-09-24)
A series of five palladium(ii) pyridyl-imine Schiff base complexes 5a-e containing boronate esters with protected sugar diols derived from d-xylose, l-sorbose and d-mannitol were designed and synthesized starting from pyridyl-imines generated in situ from 3-aminophenyl boronate ester of sugars 3a-e
Palladium-catalysed direct synthesis of benzo [b] thiophenes from thioenols.
Inamoto K, et al.
Chemical Communications (Cambridge, England), 43, 5529-5531 (2008)
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