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Merck
CN

275891

(1,5-环辛二烯)二氯化钯(II)

99%

别名:

PdCl 2 (cod)

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关于此项目

经验公式(希尔记法):
C8H12Cl2Pd
化学文摘社编号:
分子量:
285.51
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352202
EC Number:
235-161-8
MDL number:
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InChI key

RRHPTXZOMDSKRS-PHFPKPIQSA-L

InChI

1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;

SMILES string

Cl[Pd]Cl.C1CC=CCCC=C1

assay

99%

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

mp

210 °C (dec.) (lit.)

Quality Level

Application

二氯(1,5-环辛二烯)钯 (II) 是常用的保护醇类缩醛的催化剂。以丙二酸二乙酯为原料,经烯烃羰基化合成双环辛烷。也可用于催化未活化的乙烯磷酸酯与缺电子烯烃的 Heck 偶联反应;从噻吩合成苯并[b]噻吩,并制备用于 Mizoroki-Heck 和 Suzuki-Miyaura 交叉偶联反应的活性催化剂。
用于 C-C 键和 C-N 形成的催化剂,用于炔烃与烯烃的 Heck 偶联,芳基溴化物的 Suzuki 交叉偶联,肟与烯丙基乙酸酯的烯丙基取代,和碘苯的甲氧基羰基化。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

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Dichloro(1,5?cyclooctadiene)palladium(II).
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2009)
Cyclic Diolefin Complexes of Platinum and Palladium.
Inorg. Synth. (2007)
An inexpensive and highly stable ligand 1, 4-bis (2-hydroxy-3, 5-di-tert-butylbenzyl) piperazine for Mizoroki?Heck and room temperature Suzuki?Miyaura cross-coupling reactions.
Mohanty S, et al.
Tetrahedron, 64(1), 240-247 (2008)
Eda Rami Reddy et al.
Dalton transactions (Cambridge, England : 2003), 44(40), 17600-17616 (2015-09-24)
A series of five palladium(ii) pyridyl-imine Schiff base complexes 5a-e containing boronate esters with protected sugar diols derived from d-xylose, l-sorbose and d-mannitol were designed and synthesized starting from pyridyl-imines generated in situ from 3-aminophenyl boronate ester of sugars 3a-e
Palladium-catalysed direct synthesis of benzo [b] thiophenes from thioenols.
Inamoto K, et al.
Chemical Communications (Cambridge, England), 43, 5529-5531 (2008)

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