282235
甲基溴化镁 溶液
1.4 M in THF: toluene (1:3)
别名:
Bromomethylmagnesium
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关于此项目
线性分子式:
CH3MgBr
化学文摘社编号:
分子量:
119.24
UNSPSC Code:
12352111
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3535220
Concentration:
1.4 M in THF: toluene (1:3)
InChI
1S/CH3.BrH.Mg/h1H3;1H;/q;;+1/p-1
SMILES string
C[Mg]Br
InChI key
AVFUHBJCUUTGCD-UHFFFAOYSA-M
reaction suitability
reaction type: Grignard Reaction
concentration
1.4 M in THF: toluene (1:3)
density
1.018 g/mL at 25 °C
Quality Level
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Application
Methylmagnesium bromide is generally used as a Grignard reagent for C-C bond formation by reacting with the carbonyl groups of aldehydes and ketones.
signalword
Danger
Hazard Classifications
Aquatic Chronic 3 - Asp. Tox. 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3 - Water-react 1
target_organs
Central nervous system, Respiratory system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
监管及禁止进口产品
此项目有
Alcohols: Reactions and Synthesis
Organic Chemistry Study Guide: Key Concepts, Problems, and Solutions (2015)
Snahel Patel et al.
Journal of medicinal chemistry, 58(1), 401-418 (2014-10-24)
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