283673
三氟甲磺酸铜 (II)
98%
别名:
Cu(OTf)2, 三氟甲烷磺酸铜, 三氟甲磺酸 铜(II) 盐, 三氟甲磺酸铜
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关于此项目
线性分子式:
(CF3SO3)2Cu
化学文摘社编号:
分子量:
361.68
UNSPSC Code:
12161600
NACRES:
NA.22
PubChem Substance ID:
EC Number:
252-300-8
Beilstein/REAXYS Number:
4028198
MDL number:
Quality Level
assay
98%
reaction suitability
core: copper, reagent type: catalyst
mp
≥300 °C
SMILES string
FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F
InChI
1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
InChI key
SBTSVTLGWRLWOD-UHFFFAOYSA-L
Application
有效催化三甲基氰硅烷加成为羰基化合物。
可用作以下反应的催化剂：
- 曼尼希缩合反应
- 环状氨基化
- Friedel-Crafts反应
- Henry反应
- 高价碘试剂介导的咔唑制备
- 分子内氧化C-N键形成以合成咔唑
存储类别
11 - Combustible Solids
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Biswarup Chakraborty et al.
Chemistry, an Asian journal, 15(6), 852-859 (2020-02-06)
In the urge of designing noble metal-free and sustainable electrocatalysts for oxygen evolution reaction (OER), herein, a mineral Digenite Cu9 S5 has been prepared from a molecular copper(I) precursor, [{(PyHS)2 CuI (PyHS)}2 ](OTf)2 (1), and utilized as an anode material
Ahmed M Senan et al.
Journal of agricultural and food chemistry, 65(32), 6912-6918 (2017-07-19)
Utilization of renewable biomass to partly replace the fossil resources in industrial applications has attracted attention due to the limited fossil feedstock with the increased environmental concerns. This work introduced a modified Wacker-type oxidation for transformation of unsaturated fatty acids/esters
Saravanan, P. et al.
Tetrahedron Letters, 39, 3823-3823 (1998)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 283673-5G | 04061826245996 |
| 283673-25G | 04061826245989 |