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主要文件

283673

Sigma-Aldrich

三氟甲磺酸铜 (II)

98%

别名:

Cu(OTf)2, 三氟甲烷磺酸铜, 三氟甲磺酸 铜(II) 盐, 三氟甲磺酸铜

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5 G
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25 G
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5 G
CN¥1,416.77
25 G
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About This Item

线性分子式:
(CF3SO3)2Cu
CAS Number:
分子量:
361.68
Beilstein:
4028198
EC 号:
MDL编号:
UNSPSC代码:
12161600
PubChem化学物质编号:
NACRES:
NA.22

CN¥1,416.77


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质量水平

方案

98%

反应适用性

core: copper
reagent type: catalyst

mp

≥300 °C

SMILES字符串

FC(F)(F)S(=O)(=O)O[Cu]OS(=O)(=O)C(F)(F)F

InChI

1S/2CHF3O3S.Cu/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2

InChI key

SBTSVTLGWRLWOD-UHFFFAOYSA-L

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相关类别

应用

可用作以下反应的催化剂:
  • 曼尼希缩合反应
  • 环状氨基化
  • Friedel-Crafts反应
  • Henry反应
  • 高价碘试剂介导的咔唑制备
  • 分子内氧化C-N键形成以合成咔唑
有效催化三甲基氰硅烷加成为羰基化合物。[1]

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说明
价格

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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    A novel class of ditopic ligands, 1, was synthesized by the reaction of 2,5-pyrazine-dicarboxaldehyde with 2 equiv of acyl-/aroyl-hydrazine. Their structures were confirmed by 1D and 2D NMR and by X-ray crystallography. They gave heteroleptic Cu(II) dinuclear rack-like complexes of

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