285587
氟代丙二酸二乙酯
97%
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关于此项目
线性分子式:
FCH(COOC2H5)2
化学文摘社编号:
分子量:
178.16
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-684-7
Beilstein/REAXYS Number:
1775686
MDL number:
Assay:
97%
Form:
liquid
InChI key
GOWQBFVDZPZZFA-UHFFFAOYSA-N
InChI
1S/C7H11FO4/c1-3-11-6(9)5(8)7(10)12-4-2/h5H,3-4H2,1-2H3
SMILES string
CCOC(=O)C(F)C(=O)OCC
assay
97%
form
liquid
refractive index
n20/D 1.407 (lit.)
bp
121-122 °C/30 mmHg (lit.)
density
1.129 g/mL at 25 °C (lit.)
functional group
ester, fluoro
Quality Level
General description
The reaction of diethyl fluoromalonate with electron-poor and electron-rich, sterically hindered and unhindered aryl bromides and chlorides were studied.
Application
The kinetic parameters of diethyl fluoromalonate in hemolysates were used to study carboxylesterase activities in complex systems.
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
143.6 °F - closed cup
flash_point_c
62 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
G L Mendz et al.
Archives of biochemistry and biophysics, 305(2), 252-260 (1993-09-01)
Eight fluorinated compounds were tested as putative probes to measure carboxylesterase activity employing 19F nuclear magnetic resonance spectroscopy. The method takes advantage of the sensitivity of fluorine resonances to the changes in the chemical bonding in the covalent structures where
Neil A Beare et al.
The Journal of organic chemistry, 67(2), 541-555 (2002-01-19)
Palladium-catalyzed reactions of aryl bromides and chlorides with two common stabilized carbanions-enolates of dialkyl malonates and alkyl cyanoesters-are reported. An exploration of the scope of these reactions was conducted, and the processes were shown to occur in a general fashion.
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