288055
三羰基环戊二烯锰(I)
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关于此项目
线性分子式:
C5H5Mn(CO)3
化学文摘社编号:
分子量:
204.06
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
235-142-4
MDL number:
InChI key
CZPHEHHRMHXAIK-UHFFFAOYSA-N
InChI
1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;
SMILES string
[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1
Quality Level
reaction suitability
core: manganese, reagent type: catalyst
mp
72-76 °C (lit.)
signalword
Danger
hcodes
pcodes
Hazard Classifications
Acute Tox. 2 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Katrin Splith et al.
Dalton transactions (Cambridge, England : 2003), 39(10), 2536-2545 (2010-02-25)
By combining organometallic groups and peptides, a large number of conjugates with interesting new biological properties can be prepared. Especially, attachment to cell-penetrating peptides (CPP) that act as efficient cell delivery vehicles has come to the fore. However, the presence
Ines Neundorf et al.
Chemical communications (Cambridge, England), (43)(43), 5604-5606 (2008-11-11)
The conjugation of cymantrene CpMn(CO)(3) to cell-penetrating peptide hCT(18-32)-k7 alters the intracellular distribution in MCF-7 cells compared to the unmodified peptide, as visualized by fluorescence microscopy, and leads to an increased nuclear accumulation; the peptide and cymantrene compound themselves are
M Salmain et al.
Journal of immunological methods, 148(1-2), 65-75 (1992-04-08)
A new non-radioisotopic immunoassay procedure, which we have termed carbonylmetalloimmunoassay (CMIA), is described. The tracers used in this approach are organometallic carbonyl complexes that can be detected at femtomole levels (300-700 fmol) by Fourier transform infrared (FT-IR) spectroscopy. The validity
Sohrab Kheradmandan et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 8(11), 2526-2533 (2002-08-16)
The syntheses and X-ray crystal structures of [([18]crown-6)2Cs](+)-[Cp3Mn]- (1), [([18]crown-6)2Cs](+)-[Cp'3Mn]- (2), [CsCp'] (3), [(CsCp')2-([18]crown-6)] (4), and Cs[MnCp3] (5), and the synthesis of Cs[MnCp'3] (6) are reported (Cp' = C5H4Me). The anions [Cp3Mn]- (1-) and [Cp'3Mn]- (2-) are characterized by eta
K T Blanchard et al.
Toxicology and applied pharmacology, 136(2), 280-288 (1996-02-01)
Cyclopentadienyl manganese tricarbonyl (CMT) produces acute pulmonary injury following cytochrome P450 mixed-function oxidase (CYP450) activation. The current studies were designed to characterize the role of hepatic and/or pulmonary CMT activation and the subsequent pneumotoxicity of this compound following subcutaneous injection
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