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Merck
CN

288055

三羰基环戊二烯锰(I)

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线性分子式:
C5H5Mn(CO)3
化学文摘社编号:
分子量:
204.06
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
235-142-4
MDL number:
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InChI key

CZPHEHHRMHXAIK-UHFFFAOYSA-N

InChI

1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;

SMILES string

[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1

form

powder or crystals

composition

Mn, 26.0-27.9% EDTA titration

reaction suitability

core: manganese
reagent type: catalyst

mp

72-76 °C (lit.)

Quality Level

pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 2 Oral

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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I Rémy et al.
Journal of pharmaceutical and biomedical analysis, 9(10-12), 965-967 (1991-01-01)
Biotin labelled with a cymantrene moiety (cyclopentadienyl manganese tricarbonyl complex) is described for the first time. Because this metallo-biotin retains full recognition for the specific glycoprotein avidin (or streptavidin), the labelled streptavidin-biotin system is proposed for use in a solid-phase
Magdaléna Hromadová et al.
Langmuir : the ACS journal of surfaces and colloids, 22(1), 506-511 (2005-12-28)
A first example of the solid-phase immunoassay of a high-weight antigen bovine serum albumin (BSA) using an (eta(5)-cyclopentadienyl)tricarbonylmanganese (cymantrene) redox probe is presented. The electrochemical detection is based on the impedance measurements of a one-electron reversible reduction of the organometallic
K T Blanchard et al.
Toxicology letters, 70(2), 253-259 (1994-02-01)
The effect of m-xylene on the rat nasal cytochrome P450 (P450) mixed function oxidase system was analyzed in vitro utilizing microsomes isolated 2, 12, and 24 h following intraperitoneal administration of this solvent in vivo. For comparative purposes, pulmonary and
R J Clay et al.
Toxicology and applied pharmacology, 98(3), 434-443 (1989-05-01)
The acute pneumotoxic effects of cyclopentadienyl manganese tricarbonyl (CMT) and methylcyclopentadienyl manganese tricarbonyl (MMT) were compared to delineate the role of the methyl side chain in the toxicity of these organomanganese compounds and to further our understanding of the mechanisms
Katrin Splith et al.
Bioconjugate chemistry, 21(7), 1288-1296 (2010-07-01)
Over the past years, numerous promising new metalorganic lead structures have been developed exhibiting highly active cytostatic properties. However, the efficiency of such chemotherapeutics in the treatment of tumors is often limited by their low therapeutic index due to their

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