288055
三羰基环戊二烯锰(I)
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线性分子式:
C5H5Mn(CO)3
化学文摘社编号:
分子量:
204.06
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352103
EC Number:
235-142-4
MDL number:
InChI key
CZPHEHHRMHXAIK-UHFFFAOYSA-N
InChI
1S/C5H5.3CO.Mn/c1-2-4-5-3-1;3*1-2;/h1-5H;;;;
SMILES string
[Mn].[C-]#[O+].[C-]#[O+].[C-]#[O+].[CH]1[CH][CH][CH][CH]1
form
powder or crystals
composition
Mn, 26.0-27.9% EDTA titration
reaction suitability
core: manganese
reagent type: catalyst
mp
72-76 °C (lit.)
Quality Level
signalword
Danger
hcodes
pcodes
Hazard Classifications
Acute Tox. 2 Oral
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Katrin Splith et al.
Bioconjugate chemistry, 21(7), 1288-1296 (2010-07-01)
Over the past years, numerous promising new metalorganic lead structures have been developed exhibiting highly active cytostatic properties. However, the efficiency of such chemotherapeutics in the treatment of tumors is often limited by their low therapeutic index due to their
J Zayed et al.
American Industrial Hygiene Association journal, 55(1), 53-58 (1994-01-01)
Occupational and environmental exposure to airborne manganese has been measured for two groups of workers in Montreal, taxi drivers and garage mechanics. In Canada methylcyclopentadienyl manganese tricarbonyl (MMT) has replaced lead as an anti-knock agent in gasoline and represents a
Ricardo Picciochi et al.
The journal of physical chemistry. A, 112(41), 10429-10434 (2008-09-20)
The standard molar enthalpy of sublimation of monoclinic cyclopentadienyltricarbonylmanganese, Mn(eta (5)-C 5H 5)(CO) 3, at 298.15 K, was determined as Delta sub H m (o)[Mn(eta (5)-C 5H 5)(CO) 3] = 75.97 +/- 0.37 kJ x mol (-1) from Knudsen effusion
I Rémy et al.
Journal of pharmaceutical and biomedical analysis, 9(10-12), 965-967 (1991-01-01)
Biotin labelled with a cymantrene moiety (cyclopentadienyl manganese tricarbonyl complex) is described for the first time. Because this metallo-biotin retains full recognition for the specific glycoprotein avidin (or streptavidin), the labelled streptavidin-biotin system is proposed for use in a solid-phase
Magdaléna Hromadová et al.
Langmuir : the ACS journal of surfaces and colloids, 22(1), 506-511 (2005-12-28)
A first example of the solid-phase immunoassay of a high-weight antigen bovine serum albumin (BSA) using an (eta(5)-cyclopentadienyl)tricarbonylmanganese (cymantrene) redox probe is presented. The electrochemical detection is based on the impedance measurements of a one-electron reversible reduction of the organometallic
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