288063
四(亚磷酸三苯酯)镍
solid
别名:
Nickel tetrakis(triphenoxyphosphine), Tetrakis(triphenoxyphosphine)nickel, [(PhO)3P]4Ni
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关于此项目
线性分子式:
[(C6H5O)3P]4Ni
化学文摘社编号:
分子量:
1303.86
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:
产品名称
四(亚磷酸三苯酯)镍,
SMILES string
[Ni].O(P(Oc1ccccc1)Oc2ccccc2)c3ccccc3.O(P(Oc4ccccc4)Oc5ccccc5)c6ccccc6.O(P(Oc7ccccc7)Oc8ccccc8)c9ccccc9.O(P(Oc%10ccccc%10)Oc%11ccccc%11)c%12ccccc%12
InChI
1S/4C18H15O3P.Ni/c4*1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18;/h4*1-15H;
InChI key
PGXCIAAANFTEKX-UHFFFAOYSA-N
form
solid
reaction suitability
core: nickel, reagent type: catalyst
mp
145 °C (dec.) (lit.)
storage temp.
2-8°C
Quality Level
Application
Catalyst for alkene and alkyne hydrocyanation and styrenedimerization
signalword
Warning
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Fitzmaurice, N. J.; Jackson, W. R. et al.
Journal of Organometallic Chemistry, 285, 375-375 (1985)
Andell, O. S.; Baeckvall, J. E. et al.
Acta Chemica Scandinavica, B40, 184-184 (1986)
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