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Merck
CN

288462

三溴化磷

≥99.99% trace metals basis

别名:

溴化磷(III)

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关于此项目

线性分子式:
PBr3
化学文摘社编号:
分子量:
270.69
NACRES:
NA.23
PubChem Substance ID:
UNSPSC Code:
12352300
EC Number:
232-178-2
MDL number:
Assay:
≥99.99% trace metals basis
Form:
liquid
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vapor pressure

0.27 psi ( 54 °C)

Quality Level

assay

≥99.99% trace metals basis

form

liquid

refractive index

n20/D 1.697 (lit.)

bp

175 °C (lit.)

mp

−41.5 °C (lit.)

density

2.88 g/mL at 20 °C (lit.)

SMILES string

BrP(Br)Br

InChI

1S/Br3P/c1-4(2)3

InChI key

IPNPIHIZVLFAFP-UHFFFAOYSA-N

General description

Phosphorus tribromide (PBr3) is a phosphorus halide that can be used as a reactive phosphorylating agent for the formation of multifunctional thiophenes.

Application

PBr3 can be used as an acceptor molecule in the formation of donor-acceptor complexes. It can also be used in the phosphorylation of arylphospholes which can further be utilized in the synthesis of phosphonic amides.


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pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

supp_hazards

存储类别

8A - Combustible corrosive hazardous materials

wgk

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Donor-acceptor complexes between organoamines and phosphorus tribromide
Muller G, et al.
Zeitschrift fur Naturforschung B, 56(11), 1163-1171 (2001)
Site-selective phosphorylation of arylphospholes through reaction with phosphorus tribromide
Keglevich G, et al.
Journal of Organometallic Chemistry, 643(11), 32-38 (2002)
Phosphorylation of 2-(3-methyl-1, 3-diazabuten-1-yl)-3-ethoxycarbonylthiophenes with phosphorus (III) halides
Pinchuk AM, et al.
Heteroatom Chem., 12(7), 641-651 (2001)



全球贸易项目编号

货号GTIN
288462-50G04061838138811
288462-10G04061838138804