产品名称
2,5-二氟苯酚, 95%
InChI
1S/C6H4F2O/c7-4-1-2-5(8)6(9)3-4/h1-3,9H
SMILES string
Oc1cc(F)ccc1F
InChI key
INXKVYFOWNAVMU-UHFFFAOYSA-N
assay
95%
form
solid
mp
40-42 °C (lit.)
functional group
fluoro
Quality Level
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General description
Conversion of 2,5-difluorophenol by whole cells of Rhodococcus opacus 1G has been investigated by 9F NMR analysis.
Application
2,5-Difluorophenol has been used in the synthesis of di- or trifluorinated hydroxybenzoic acids.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
127.4 °F - closed cup
flash_point_c
53 °C - closed cup
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
The regioexhaustive functionalization of difluorophenols and trifluorophenols through organometallic intermediates.
Marzi E, et al.
Synthesis, 2004(10), 1609-1618 (2004)
V S Bondar et al.
FEMS microbiology letters, 181(1), 73-82 (1999-11-24)
The regiospecificity of hydroxylation of C2-halogenated phenols by Rhodococcus opacus 1G was investigated. Oxidative defluorination at the C2 position ortho with respect to the hydroxyl moiety was preferred over hydroxylation at the non-fluorinated C6 position for all 2-fluorophenol compounds studied.
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