302767
(S)-(-)-1-甲基-2-吡咯烷甲醇
96%
别名:
N-甲基-L-脯氨醇, (S)-2-羟甲基-1-甲基吡咯烷
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关于此项目
经验公式（希尔记法）:
C6H13NO
化学文摘社编号:
分子量:
115.17
UNSPSC Code:
12352209
NACRES:
NA.22
PubChem Substance ID:
EC Number:
251-981-9
Beilstein/REAXYS Number:
79851
MDL number:
产品名称
(S)-(-)-1-甲基-2-吡咯烷甲醇, 96%
form
liquid
assay
96%
InChI key
VCOJPHPOVDIRJK-LURJTMIESA-N
InChI
1S/C6H13NO/c1-7-4-2-3-6(7)5-8/h6,8H,2-5H2,1H3/t6-/m0/s1
SMILES string
CN1CCC[C@H]1CO
optical activity
[α]19/D −49.5°, c = 5 in methanol
reaction suitability
reaction type: solution phase peptide synthesis
refractive index
n20/D 1.469 (lit.)
bp
67-69 °C/12 mmHg (lit.)
density
0.968 g/mL at 25 °C (lit.)
application(s)
peptide synthesis
storage temp.
2-8°C
Quality Level
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Application
膦配体的前体，可用于催化不对称格氏交叉偶联反应。
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Dan Loewenthal et al.
Archives of toxicology, 94(11), 3751-3757 (2020-07-29)
We present a simple method for chiral separation and analysis of organophosphorus nerve agents and apply it to monitor the enantioselective blood elimination kinetics of sarin in-vitro. The method is implemented in standard reverse phase LC-MS operating conditions, relieving the
The Journal of Organic Chemistry, 48, 2195-2195 (1983)
商品
Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.
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